Highly efficient alcohol oxidation catalyzed by palladium(II)-alkylamine complexes using atmospheric molecular oxygen

被引：12

作者：

Shimazu, Shogo ^{[1
]}

Uehara, Tae ^{[1
]}

Asami, Aki ^{[1
]}

Hara, Takayoshi ^{[1
]}

Ichikuni, Nobuyuki ^{[1
]}

机构：

[1] Chiba Univ, Dept Appl Chem & Biotechnol, Grad Sch Engn, Inage Ku, Chiba 2638522, Japan

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2008年 / 282卷 / 1-2期

关键词：

alcohol oxidation; molecular oxygen; palladium(II)-alkylamine complex;

D O I：

10.1016/j.molcata.2007.10.036

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Two series of palladium(II)-alkylamine (Pd(Me(2)NCn)(2)(OAc)(2), Me(2)NCn: N,N'-dimethylalkylamine, n = 4, 8, 12, and 16) and palladium(II) N,N'-dialkylamine (Pd(Cn(2)NH)(2)(OAc)(2), Cn(2)NH: N,N'-dialkylamine, n=4,8, and 12) were prepared. These homogeneous Pd complexes catalyzed the aerobic oxidation of wide range of alcohols into the corresponding aldehydes and ketones efficiently. For example, a benzylalcohol oxidation proceeded rapidly by means of Pd(Me(2)NCl2)(2)(OAc)(2) with an excellent turnover frequency of up to 96 h(-1). (C) 2007 Elsevier B.V. All rights reserved.

引用

页码：28 / 33

页数：6

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