(μ-Benzoato-κ2O:O′)tris[μ-N,N′-bis(4-methoxyphenyl)formamidinato-κ2N:N′]dimolybdenum(II) dichloromethane monosolvate

被引：2
|
作者：
Han, L-J. [1 ]
机构：
[1] Tongji Univ, Dept Chem, Shanghai 200092, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷
关键词：
D O I：
10.1107/S1600536811002558
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, [Mo-2(C15H15N2O2)(3)(C7H5O2)]center dot CH2Cl2, has a quadruply bonded Mo-2(4+) unit equatorially coordinated by three N,N '-bis(4-mu-methoxyphenyl)formamidinate (DAniF) ligands and one benzoate anion. The Mo-Mo bond length of 2.0881 (8) angstrom is typical for quadruply bonded species. The phenyl ring and the connected dimetal chelating ring (Mo2O2C) are nearly co-planar, making a dihedral angle of 3.24 (13)degrees. The dichloromethane solvent molecule is disordered over four sets of sites with occupancies of 0.3:0.3:0.2:0.2.
引用
收藏
页码：M256 / U1546
页数：17
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