Novel single-layer gas diffusion layer based on PTFE/carbon black composite for proton exchange membrane fuel cell

被引:45
|
作者
Chen-Yang, Y. W. [1 ]
Hung, T. F.
Huang, J.
Yang, F. L.
机构
[1] Chung Yuan Christian Univ, Dept Chem, Chungli 32023, Taiwan
[2] Chung Yuan Christian Univ, Ctr Nanotechnol, Chungli 32023, Taiwan
[3] Yeu Ming Tai Chem Ind Co Ltd, Taichung 40768, Taiwan
关键词
gas diffusion layer; proton exchange membrane fuel cell; poly(tetrafluoroethylene); carbon black; wet-proof treatment; microporouslayer;
D O I
10.1016/j.jpowsour.2007.04.080
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A series of poly(tetrafluoroethylene)/carbon black composite-based single-layer gas diffusion layers (PTFE/CB-GDLs) for proton exchange membrane fuel cell (PEMFC was successfully prepared from carbon black and un-sintered PTFE, which included powder resin and colloidal dispersion, by a simple inexpensive method. The scanning electron micrographs of PTFE/CB-GDLs indicated that the PTFE resins were homogeneously dispersed in the carbon black matrix and showed a microporous layer (MPL)-like structure. The as-prepared PTFE/CB-GDLs exhibited good mechanical property, high gas permeability, and sufficient water repellency. The best current density obtained from the PEMFC with the single-layer PTFE/CB-GDL was 1.27 and 0.42 A cm(-2) for H-2/O-2 and H-2/air system, respectively. (C) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:183 / 188
页数:6
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