Tubular crystals growth for a nanoporous hydrogen-bonded metal-organic framework

被引：23
|
作者：
Mouchaham, Georges [1 ,2 ]
Roques, Nans [1 ,2 ]
Kaiba, Abdellah [3 ]
Guionneau, Philippe [3 ]
Sutter, Jean-Pascal [1 ,2 ]
机构：
[1] CNRS, Chim Coordinat Lab, F-31077 Toulouse, France
[2] Univ Toulouse, UPS, INPT, LCC, F-31077 Toulouse, France
[3] Univ Bordeaux, CNRS, ICMCB, F-33608 Pessac, France
来源：
CRYSTENGCOMM | 2010年 / 12卷 / 11期
关键词：
MOLECULAR TECTONICS; ZEOLITIC FEATURES; BUILDING UNIT; ARCHITECTURES; CHEMISTRY;
D O I：
10.1039/c0ce00256a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A supramolecular architecture formed by H-bonded assemblage of ditopic bisimidazoliumbenzene cations with anionic metal-oxalate modules shows permanent porosity upon guests release; the reversible sorption process being accompanied by crystal-to-crystal transformations. Additional macroporosity for the material was achieved by controlled growth of crystals with tubular morphology.
引用
收藏
页码：3496 / 3498
页数：3
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