Reactions of 8-methoxyquinoline [C10H9ON] and diorganotin dichlorides.: Crystal structures of [C10H9ON.H]2Ph2SnCl4 and [C10H9ON.H.NOH9C10]Ph2SnCl3

被引：19
|
作者：
Ouyang, J [1 ]
Xu, Y [1 ]
Khoo, LE [1 ]
机构：
[1] Nanyang Technol Univ, Sch Sci, Singapore 259756, Singapore
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1998年 / 561卷 / 1-2期
关键词：
8-methoxyquinoline; diorganotin dichlorides; distannoxanes; crystal structure of organostannate salts of 8-methoxyquinoline;
D O I：
10.1016/S0022-328X(98)00509-9
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reactions of 8-methoxyquinoline (C10H9ON) with R2SnCl2 (R = Ph, Me, n-Bu) have been investigated. All these reactions yielded the corresponding distannoxanes, [(R2SnCl)(2)O](2), 8-methoxyquinolinium chloride for R = n-Bu and organostannate salts for R = Ph, Me. The central tin atom of the stannate salts is not bonded to the two N and O donor atoms of the ligand species. X-ray structural analysis was performed on the complexes, [C10H9ON . H . NOH9C10]Ph2SnCl3 and [C10H9ON . H](2)Ph2SnCl4, and the results along with those obtained from a variety of physical measurements for these products are discussed. In addition, it was found that the Ph2SnCl3- moiety present in [C10H9ON . H . NOH9C10]Ph2SnCl3 disproportionated into Ph2SnCl2 and Ph2SnCl42-. (C) 1998 Elsevier Science S.A. All rights reserved.
引用
收藏
页码：143 / 152
页数：10
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