PHOTOCHEMISTRY AND PHOTOPHYSICS OF METAL COMPLEXES WITH DENDRITIC LIGANDS

被引：10

作者：

Balzani, Vincenzo ^{[1
]}

Bergamini, Giacomo ^{[1
]}

Ceroni, Paola ^{[1
]}

机构：

[1] Univ Bologna, Dipartimento Chim G Ciamician, I-40126 Bologna, Italy

来源：

ADVANCES IN INORGANIC CHEMISTRY, VOL 63: INORGANIC PHOTOCHEMISTRY | 2011年 / 63卷

关键词：

Luminescence; Energy transfer; Electron transfer; Lanthanide ions; Sensors; POLY(PROPYLENE AMINE) DENDRIMERS; ABSORPTION-SPECTRA; ENERGY-TRANSFER; POLYPYRIDINE COMPLEXES; CYCLAM CORE; LUMINESCENCE PROPERTIES; RUTHENIUM(II) COMPLEX; LANTHANIDE COMPLEXES; POLYLYSIN DENDRIMER; FLUORESCENT SENSORS;

D O I：

10.1016/B978-0-12-385904-4.00008-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Combinations of suitably chosen metal ions and dendritic ligands may lead to giant metal complexes that display interesting spectroscopic properties, particularly as far as luminescence is concerned. This chapter illustrates some fundamental aspects of the interaction of light with dendrimers and then reviews results obtained with dendrimers (i) containing one or more metal complexes as branching centers or as a core, (ii) capable of coordinating one or more metal ions in their cavities, (iii) assembled around metal ions without or with other ligands. The study of the luminescent properties reveals that these compounds can be useful for several purposes, including light harvesting, sensing with signal amplification, conversion of the absorbed light into emitted light of quite different wavelengths (e.g., UV light into IR light), and information processing.

引用

页码：105 / 135

页数：31

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