X-ray emission-photoion coincidence spectroscopy of the CO2 molecule at the O 1s edge

被引：4
|
作者：
Kivimaeki, A. [1 ]
Alagia, M. [1 ]
Richter, R. [2 ]
机构：
[1] Lab TASC, CNR IOM, I-34149 Trieste, Italy
[2] Sincrotrone Trieste, I-34149 Trieste, Italy
来源：
CHEMICAL PHYSICS LETTERS | 2012年 / 531卷
关键词：
CARBON-DIOXIDE; PHOTOELECTRON-SPECTRUM; SYMMETRY-BREAKING; CROSS-SECTIONS; GAS-PHASE; CORE; EXCITATIONS; IONIZATION; THRESHOLD; ENERGY;
D O I：
10.1016/j.cplett.2012.02.022
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Molecular dissociation following radiative decay of O 1s hole states in CO2 has been studied by detecting photoions in coincidence with undispersed soft X-ray emission. The production of ions after radiative decay is observed to increase from practically nothing at the O 1s -> pi* excitation to the appearance of CO2+, CO+, C+ and O+ ions when core-valence double excitations and O 1s shake-up transitions are induced. De-excitation pathways involving radiative decay from different core-hole states are discussed in order to interpret the results. A weak CO22+ signal is attributed to the radiative Auger effect. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码：252 / 256
页数：5
相关论文
共 50 条
  • [41] Theory of oxygen 1s resonant X-ray emission in edge-share-type quasi-one-dimensional cuprates
    Okada, K
    Kotani, A
    JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 2003, 72 (04) : 797 - 800
  • [42] Li 1s core exciton in LiH studied by x-ray Raman scattering spectroscopy
    Paredes-Mellone, O. A.
    Stutz, G. E.
    Ceppi, S. A.
    Arneodo Larochette, P.
    Huotari, S.
    Gilmore, K.
    JOURNAL OF PHYSICS-CONDENSED MATTER, 2019, 31 (05)
  • [43] The C 1s and N 1s near edge x-ray absorption fine structure spectra of five azabenzenes in the gas phase
    Vall-llosera, G.
    Gao, B.
    Kivimaeki, A.
    Coreno, M.
    Ruiz, J. Alvarez
    de Simone, M.
    Agren, H.
    Rachlew, E.
    JOURNAL OF CHEMICAL PHYSICS, 2008, 128 (04):
  • [44] Substituent effects in the iron 2p and carbon 1s edge near-edge X-ray absorption fine structure (NEXAFS) spectroscopy of ferrocene compounds
    Otero, E.
    Wilks, R. G.
    Regier, T.
    Blyth, R. I. R.
    Moewes, A.
    Urquhart, S. G.
    JOURNAL OF PHYSICAL CHEMISTRY A, 2008, 112 (04): : 624 - 634
  • [45] A STUDY OF THE 1S CORE REGION OF ATOMIC MAGNESIUM BY X-RAY PHOTOELECTRON-SPECTROSCOPY
    BANNA, MS
    SLAUGHTER, AR
    MATHEWS, RD
    KEY, RJ
    BALLINA, SM
    CHEMICAL PHYSICS LETTERS, 1982, 92 (02) : 122 - 124
  • [46] Nitrogen 1s near-edge X-ray absorption fine structure spectroscopy of amino acids: Resolving zwitterionic effects
    Otero, Edwige
    Urquhart, Stephen G.
    JOURNAL OF PHYSICAL CHEMISTRY A, 2006, 110 (44): : 12121 - 12128
  • [47] Practical guides for x-ray photoelectron spectroscopy (XPS): Interpreting the carbon 1s spectrum
    Gengenbach, Thomas R.
    Major, George H.
    Linford, Matthew R.
    Easton, Christopher D.
    JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A, 2021, 39 (01):
  • [48] Angle-resolved photoelectron spectroscopy of the satellite bands accompanying the O 1s mainline of CO2
    Hoshino, M
    Tanaka, I
    Kitajima, M
    De Fanis, A
    Tanaka, H
    Pavlychev, AA
    Ueda, K
    JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, 2005, 144 : 203 - 205
  • [49] Origin of fine structures on the dissociative 1s→σ* resonance in X-ray absorption spectra of O2
    Velkov, Yasen
    Kimberg, Victor
    Kosugi, Nobuhiro
    Salek, Pawel
    Gel'mukhanov, Faris
    CHEMICAL PHYSICS LETTERS, 2009, 476 (4-6) : 147 - 150
  • [50] Resonant inelastic x-ray scattering and UV-VUV luminescence at the Be 1s edge in BeO
    Kikas, A.
    Kaambre, T.
    Kooser, K.
    Kuusik, I.
    Kisand, V.
    Nommiste, E.
    Kirm, M.
    Feldbach, E.
    Ivanov, V.
    Pustovarov, V.
    Martinson, I.
    JOURNAL OF PHYSICS-CONDENSED MATTER, 2010, 22 (37)
12345