The adsorption and electrochemical behavior of Mo(VI) complexes on the surface of a graphite electrode is studied. A mechanism for generation of the analyte signal in a "graphite - Mo(VI) complex - arsenic(V)" system is proposed. An inversion voltammetric method for determination of arsenic(V) in the concentration range of 3 x 10(-9) - 8 x 10(-8) M is described.
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Univ Queensland, Sch Agr & Food Sci CRC CARE, St Lucia, Qld 4072, AustraliaUniv Queensland, Sch Agr & Food Sci CRC CARE, St Lucia, Qld 4072, Australia
Hua, T.
Haynes, R. J.
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Univ Queensland, Sch Agr & Food Sci CRC CARE, St Lucia, Qld 4072, AustraliaUniv Queensland, Sch Agr & Food Sci CRC CARE, St Lucia, Qld 4072, Australia
Haynes, R. J.
Zhou, Y. -F.
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Univ Queensland, Sch Agr & Food Sci CRC CARE, St Lucia, Qld 4072, AustraliaUniv Queensland, Sch Agr & Food Sci CRC CARE, St Lucia, Qld 4072, Australia
Zhou, Y. -F.
Boullemant, A.
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Rio Tinto, Legacy Management Europe, F-38341 Voreppe, FranceUniv Queensland, Sch Agr & Food Sci CRC CARE, St Lucia, Qld 4072, Australia
Boullemant, A.
Chandrawana, I.
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Rio Tinto Alcan, Queensland Res & Dev Ctr, Brisbane, Qld 4069, AustraliaUniv Queensland, Sch Agr & Food Sci CRC CARE, St Lucia, Qld 4072, Australia