Synthesis and crystal structure of lithium ethylenediaminetetraacetatobismuthate(III) tetrahydrate

被引：0
|
作者：
Davidovich, RL [1 ]
Gerasimenko, AV [1 ]
Logvinova, VB [1 ]
机构：
[1] Russian Acad Sci, Inst Chem, Far E Div, Vladivostok 660022, Russia
来源：
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2001年 / 46卷 / 09期
关键词：
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The LiBi(Edta) . 4H(2)O complex was synthesized for the first time, and its crystal structure was determined. The structure consists of Li(H2O)(2)(+) aqua cations, [Bi(Edta)](-) complex anions, and crystal water molecules. The coordination number of the Bi atom in the complex is equal to 7. The Li(H2O)(2)(+) cations and neighboring [Bi(Edta)](-) complex anions are united into zigzag polymeric chains through the carbonyl oxygen atoms (O(2) and O(8)'). The polymeric chains form infinite layers, with crystal water molecules between them, through bridging bonds with the O(6)' carbonyl oxygen atoms of neighboring chains.
引用
收藏
页码：1333 / 1338
页数：6
相关论文
共 50 条
  • [41] Discrete complex anion [Bi(Edta)(H2O)]- of seven-coordinate bismuth:: Synthesis and crystal structure of thiosemicarbazidium ethylenediaminetetraacetatobismuthate(III) monohydrate
    Davidovich, RL
    Gerasimenko, AV
    Logvinova, VB
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2001, 46 (07) : 967 - 972
  • [42] Complexes of bismuth(III) with aminopolycarboxylic acids. Crystal structures of guanidinium aqua(ethylenediamineteraacetato)bismuthate(III) and aminoguanidinium ethylenediaminetetraacetatobismuthate(III)
    Ilyukhin, AB
    Davidovich, RL
    Logvinova, VB
    Fun, HK
    Raj, SSS
    Razak, IA
    Hu, SZ
    Ng, SW
    MAIN GROUP METAL CHEMISTRY, 1999, 22 (05): : 275 - 281
  • [43] STRUCTURE OF TRIAQUA(NITRILOTRIACETATO)VANADIUM(III) TETRAHYDRATE
    OKAMOTO, K
    HIDAKA, J
    FUKAGAWA, M
    KANAMORI, K
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1992, 48 : 1025 - 1027
  • [44] SYNTHESIS AND CHARACTERIZATION OF CESIUM TETRACHLOROURANATE(III) TETRAHYDRATE
    KARBOWIAK, M
    DROZDZYNSKI, J
    JOURNAL OF THE LESS-COMMON METALS, 1990, 163 (01): : 159 - 164
  • [45] Synthesis, Characterization, and Crystal Structure of Lithium Pyrrolide
    Jing, Zijun
    Tan, Khai Chen
    He, Teng
    Yu, Yang
    Pei, Qijun
    Wang, Jintao
    Wu, Hui
    Chen, Ping
    ACTA PHYSICO-CHIMICA SINICA, 2021, 37 (11)
  • [46] CRYSTAL-STRUCTURE AND EPR-SPECTRUM OF BISPYRIDINIUM BIS(CITRATO)CHROMIUM(III) TETRAHYDRATE
    QUIROS, M
    GOODGAME, DML
    WILLIAMS, DJ
    POLYHEDRON, 1992, 11 (11) : 1343 - 1348
  • [47] REFINEMENT OF CRYSTAL STRUCTURE OF BERYLLIUM SULPHATE TETRAHYDRATE
    DANCE, IG
    FREEMAN, HC
    ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL CRYSTALLOGRAPHY AND CRYSTAL CHEMISTRY, 1969, B 25 : 304 - +
  • [48] CRYSTAL AND MOLECULAR STRUCTURE OF HEXAAQUOALUMINUM HEXACHLORORUTHENATE TETRAHYDRATE
    HOPKINS, TE
    ZALKIN, A
    TEMPLETO.DH
    ADAMSON, MG
    INORGANIC CHEMISTRY, 1969, 8 (11) : 2421 - &
  • [49] CRYSTAL-STRUCTURE OF ZIRCONIUM ETHYLENEDIAMINETETRAACETATE TETRAHYDRATE
    POZHIDAEV, AI
    PORAIKOSHITS, MA
    POLYNOVA, TN
    JOURNAL OF STRUCTURAL CHEMISTRY, 1974, 15 (04) : 548 - 553
  • [50] CRYSTAL-STRUCTURE OF MANGANESE ACETATE TETRAHYDRATE
    BERTAUT, EF
    DUC, TQ
    BURLET, P
    THOMAS, M
    MOREAU, JM
    ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1974, 30 (SEP15): : 2234 - 2236
12345