Hollow cubic ZnSnO3 with abundant oxygen vacancies for H2S gas sensing

被引:58
|
作者
Wang, Zheying [1 ]
Miao, Jiayu [1 ]
Zhang, Haixue [1 ]
Wang, Dong [2 ]
Sun, Jianbo [1 ]
机构
[1] Harbin Normal Univ, Sch Phys & Elect Engn, Key Lab Photon & Elect Bandgap Mat, Minist Educ, Harbin 10025, Peoples R China
[2] Northeast Elect Power Univ, 169 Changchun Rd, Jilin 132012, Jilin, Peoples R China
基金
中国国家自然科学基金;
关键词
Hollow cubic; ZnSnO3; Oxygen vacancies; Gas sensor; H2S; OXIDE; NANOCOMPOSITE; MICROSPHERES; FABRICATION;
D O I
10.1016/j.jhazmat.2020.122226
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The hollow cubic structure ZnSnO3 with controllable concentration of oxygen vacancies were prepared by the hydrothermal combined with alkali etching method. The morphology and structure of the materials were analyzed by X-ray diffraction (XRD), electron scanning electron microscopy (FE-SEM) and transmission electron microscopy (TEM). The resistance-type sensor with the hollow cubic ZnSnO3 as sensing material was fabricated. The sensor exhibited high sensing performance for H2S. The oxygen vacancy was studied by X-ray photoelectron spectroscopy (XPS) and photoluminescence (PL) spectrum. Besides, the possible gas-sensitive mechanism was discussed.
引用
收藏
页数:9
相关论文
共 50 条
  • [21] Highly sensitive sensing platform based on ZnSnO3 hollow cubes for detection of ethanol
    Zhou, Tingting
    Zhang, Tong
    Zhang, Rui
    Deng, Jianan
    Lou, Zheng
    Lu, Geyu
    Wang, Lili
    APPLIED SURFACE SCIENCE, 2017, 400 : 262 - 268
  • [22] One-pot synthesis of cubic ZnSnO3/ZnO heterostructure composite and enhanced gas-sensing performance
    Yan, Yan
    Liu, Jingyuan
    Zhang, Hongsen
    Song, Dalei
    Li, Junqing
    Yang, Piaoping
    Zhang, Milin
    Wang, Jun
    JOURNAL OF ALLOYS AND COMPOUNDS, 2019, 780 : 193 - 201
  • [23] Enhanced UV detection of ZnSnO3 hollow spheres: Dark current inhibition from excitons and homostructures based on excitation of oxygen vacancies
    Liu, Changju
    Wang, Xiuyu
    Ren, Qun
    Yang, Zhe
    Cui, Yuang
    Xu, Jiangtao
    CERAMICS INTERNATIONAL, 2023, 49 (09) : 14459 - 14469
  • [24] Morphology-controlled synthesis of ZnSnO3 hollow spheres and their n-butanol gas-sensing performance
    Feng, Guoqing
    Che, Yanhan
    Song, Chengwen
    Xiao, Jingkun
    Fan, Xinfei
    Sun, Shuang
    Huang, Guohui
    Ma, Yanchao
    CERAMICS INTERNATIONAL, 2021, 47 (02) : 2471 - 2482
  • [25] Preparation, structure and gas-sensing properties of ultramicro ZnSnO3 powder
    Shen, Yu-Sheng
    Zhang, Tian-Shu
    Sensors and Actuators, B: Chemical, 1993, B12 (01) : 5 - 9
  • [26] Ethanol gas sensing property and mechanism of ZnSnO3 doped with Ti ions
    Zeng, Wen
    Liu, Tian-mo
    Lin, Li-yang
    MATERIALS SCIENCE IN SEMICONDUCTOR PROCESSING, 2012, 15 (03) : 319 - 325
  • [27] Facile fabrication and enhanced gas sensing properties of ZnSnO3/NiO heterostructures
    Du, Liyong
    Sun, Heming
    JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2022, 33 (19) : 15734 - 15741
  • [28] PREPARATION, STRUCTURE AND GAS-SENSING PROPERTIES OF ULTRAMICRO ZNSNO3 POWDER
    SHEN, YS
    ZHANG, TS
    SENSORS AND ACTUATORS B-CHEMICAL, 1993, 12 (01) : 5 - 9
  • [29] Facile fabrication and enhanced gas sensing properties of ZnSnO3/NiO heterostructures
    Liyong Du
    Heming Sun
    Journal of Materials Science: Materials in Electronics, 2022, 33 : 15734 - 15741
  • [30] Microstructure and Gas-Sensing Property of Titania-Added ZnSnO3
    Zeng, Wen
    Liu, Tianmo
    Wang, Zhongchang
    MATERIALS TRANSACTIONS, 2010, 51 (07) : 1326 - 1329