Response to "Comment on 'Anharmonic properties of the vibrational quantum computer' " [J. Chem. Phys. 128, 167101 (2008)]

被引:4
|
作者
Babikov, Dmitri [1 ]
Zhao, Meiyu [1 ]
机构
[1] Marquette Univ, Dept Chem, Milwaukee, WI 53201 USA
来源
JOURNAL OF CHEMICAL PHYSICS | 2008年 / 128卷 / 16期
关键词
D O I
10.1063/1.2907733
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A benchmark study of the approximate approach to the optimal control of vibrational qubits, which was used in the original paper [J. Chem. Phys.126, 204102 (2007)], is presented. Two simplified assumptions are used in this method: A linear approximation for the dipole moment function and a harmonic approximation for the vibrational wave functions. Both assumptions are often used in spectroscopy and are known to work well for many molecules when the vibrational excitation is low. Here, we show that our method works well for the OH molecule, which exhibits a very anharmonic spectrum of vibrational eigenstates and a complicated dipole moment function.
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页数:3
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