Synthesis of Functional Poly(propargyl imine)s by Multicomponent Polymerizations of Bromoarenes, Isonitriles, and Alkynes

被引：21
|
作者：
Huang, Hanchu [1 ,2 ]
Qiu, Zijie [1 ,2 ]
Han, Ting [1 ,2 ]
Kwok, Ryan T. K. [1 ,2 ]
Lam, Jacky W. Y. [1 ,2 ,3 ]
Tang, Ben Zhong [1 ,2 ,3 ]
机构：
[1] Hong Kong Univ Sci & Technol, Hong Kong Branch,Inst Adv Study, State Key Lab Mol Neurosci,Chinese Natl Engn Res, Inst Mol Funct Mat,Div Biomed Engn,Dept Chem,Div, Kowloon, Hong Kong, Peoples R China
[2] HKUST Shenzhen Res Inst, Guangdong Prov Key Lab Brain Sci Dis & Drug Dev, 9 Yuexing 1st RD,South Area,Hitech Pk, Shenzhen 518057, Peoples R China
[3] South China Univ Technol, SCUT HKUST Joint Res Lab, State Key Lab Luminescent Mat & Devices, Guangdong Innovat Res Team, Guangzhou 510640, Peoples R China
来源：
ACS MACRO LETTERS | 2017年 / 6卷 / 12期
基金：
美国国家科学基金会;
关键词：
AGGREGATION-INDUCED EMISSION; ALDEHYDES; MACROMOLECULES; CHEMISTRY; POLYMERS; LIBRARY; DIYNES; AMINES;
D O I：
10.1021/acsmacrolett.7b00872
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Here we reported a versatile and multicomponent polymerization (MCP) approach that enabled the synthesis of functional poly(propargyl imine)s with well-defined structures and high molecular weight (M-w up to 38 200) in excellent yields (up to 93%) from readily accessible monomers of dibromoarenes, isonitriles, and diynes. This MCP had the advantages of simple operation, wide substrate scope, and mild reaction conditions. The resulting polymers possessed good solubility and showed high thermal stability and refractive indices. The tetraphenylethene-containing polymer displayed a phenomenon of aggregation-induced emission and could respond to various acidic vapors.
引用
收藏
页码：1352 / 1356
页数：5
相关论文
共 50 条
  • [41] Room-Temperature Metal-Free Multicomponent Polymerizations of Elemental Selenium toward Stable Alicyclic Poly(oxaselenolane)s with High Refractive Index
    Wu, Xiuying
    He, Junxia
    Hu, Rongrong
    Tang, Ben Zhong
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2021, 143 (38) : 15723 - 15731
  • [42] Palladium-Catalyzed Polymerization of Perfluoroalkyl Iodide and Aromatic Alkynes for the Synthesis of Perfluoroalkylated Poly(enyne)s
    Tian, Wen
    Yao, Guanfei
    Hu, Rongrong
    Tang, Ben Zhong
    MACROMOLECULAR CHEMISTRY AND PHYSICS, 2023, 224 (01)
  • [43] Synthesis of Pyrrole-Based Poly(arylenevinylene)s via Co-Catalyzed Hydroarylation of Alkynes
    Iwamori, Ryota
    Sato, Ryota
    Kuwabara, Junpei
    Yasuda, Takeshi
    Kanbara, Takaki
    MACROMOLECULAR RAPID COMMUNICATIONS, 2021, 42 (16)
  • [44] Synthesis of thermally crosslinkable fluorine-containing poly(arylene ether ketone)s - II. Propargyl ether terminated poly(arylene ether ketone)s
    Kimura, K
    Nishichi, A
    Yamashita, Y
    POLYMERS FOR ADVANCED TECHNOLOGIES, 2004, 15 (06) : 313 - 319
  • [45] Synthesis of Reprocessable Lignin-based Non-isocyanate Poly(imine-hydroxyurethane)s Networks
    Danwei Xue
    Bailiang Xue
    Rui Tang
    Chao Shen
    Xinping Li
    Wei Zhao
    Paper and Biomaterials, 2021, 6 (01) : 11 - 21
  • [46] Synthesis, characterization, thermal and electrochemical features of poly (phenoxy-imine)s containing pyridine and pyrimidine units
    Hatice Karaer Yağmur
    İsmet Kaya
    Haluk Aydın
    Journal of Polymer Research, 2020, 27
  • [47] Synthesis, characterization, thermal and electrochemical features of poly (phenoxy-imine)s containing pyridine and pyrimidine units
    Yagmur, Hatice Karaer
    Kaya, Ismet
    Aydin, Haluk
    JOURNAL OF POLYMER RESEARCH, 2020, 27 (12)
  • [48] Synthesis and Characterizations of Poly(phenoxy-Imine)s via Catalyzed Oxidative Polymerization by Polymer–Metal Complex
    Dilek Şenol
    İsmet Kaya
    Arabian Journal for Science and Engineering, 2017, 42 : 2381 - 2396
  • [49] Room-temperature polymerizations of selenium and alkynones for the regioselective synthesis of poly(1,4-diselenin)s or polyselenophenes
    Peng, Jianwen
    Zheng, Nan
    Shen, Pingchuan
    Zhao, Zujin
    Hu, Rongrong
    Tang, Ben Zhong
    CHEM, 2022, 8 (08): : 2301 - 2316
  • [50] Design of catalytic carbonylative polymerizations of heterocycles.: Synthesis of polyesters and amphiphilic poly(amide-block-ester)s
    Liu, GS
    Jia, L
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (45) : 14716 - 14717
12345