Recent advances in the sulfonylation of C-H bonds with the insertion of sulfur dioxide

被引：188

作者：

Qiu, Guanyinsheng ^{[1
,2
]}

Zhou, Kaida ^{[2
]}

Wu, Jie ^{[2
,3
]}

机构：

[1] Jiaxing Univ, Coll Biol Chem Sci & Engn, 118 Jiahang Rd, Jiaxing 314001, Peoples R China

[2] Fudan Univ, Dept Chem, 2005 Songhu Rd, Shanghai 200438, Peoples R China

[3] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, 345 Lingling Rd, Shanghai 200032, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2018年 / 54卷 / 89期

基金：

中国博士后科学基金; 中国国家自然科学基金;

关键词：

PALLADIUM-CATALYZED SYNTHESIS; 3-COMPONENT REACTION; ONE-POT; PHOTOREDOX CATALYSIS; C(SP(3))-H BONDS; DIRECT ARYLATION; 8-AMINOQUINOLINE AMIDES; MULTICOMPONENT REACTION; DIARYLIODONIUM SALTS; ALIPHATIC AMIDES;

D O I：

10.1039/c8cc07434h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Recent advances in the sulfonylation of C-H bonds with the insertion of sulfur dioxide are summarized. Usually, a sulfur dioxide surrogate, DABCO(SO2)(2), is used, which avoids the utilization of gaseous sulfur dioxide in the transformation. Inorganic sulfites such as sodium metabisulfite are also effective in C(sp(3))-H bond sulfonylation. C-H bond sulfonylation under transition metal catalysis or through a radical process has been developed. In some cases, the sulfonylation can be performed under catalyst- and additive-free conditions, or can be facilitated by visible light irradiation. The efficiency is also investigated by merging the radical process and metal catalysis.

引用

页码：12561 / 12569

页数：9

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