human error;
expert judgment;
measurement uncertainty;
quality risk management;
measurement and testing laboratory;
chemical analysis;
ANALYTICAL-CHEMISTRY;
EXPERT JUDGMENTS;
ICP-MS;
QUANTIFICATION;
D O I:
10.1088/0026-1394/52/2/238
中图分类号:
TH7 [仪器、仪表];
学科分类号:
0804 ;
080401 ;
081102 ;
摘要:
Evaluating the residual risk of human errors in a measurement and testing laboratory, remaining after the error reduction by the laboratory quality system, and quantifying the consequences of this risk for the quality of the measurement/test results are discussed based on expert judgments and Monte Carlo simulations. A procedure for evaluation of the contribution of the residual risk to the measurement uncertainty budget is proposed. Examples are provided using earlier published sets of expert judgments on human errors in pH measurement of groundwater, elemental analysis of geological samples by inductively coupled plasma mass spectrometry, and multi-residue analysis of pesticides in fruits and vegetables. The human error contribution to the measurement uncertainty budget in the examples was not negligible, yet also not dominant. This was assessed as a good risk management result.
机构:
EMPA St Gallen, Swiss Fed Labs Mat Testing & Res, CH-9014 St Gallen, SwitzerlandEMPA St Gallen, Swiss Fed Labs Mat Testing & Res, CH-9014 St Gallen, Switzerland