Electrodeposition of Tin Based Film on Copper Plate for Electrocatalytic Reduction of Carbon Dioxide to Formate

被引：12
|
作者：
Lv, Weixin [1 ]
Zhou, Jing [1 ]
Bei, Jingjing [1 ]
Zhang, Rui [1 ]
Kong, Fenying [1 ]
Wang, Wei [1 ]
机构：
[1] Yancheng Inst Technol, Sch Chem & Chem Engn, Yancheng 224051, Peoples R China
来源：
INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE | 2016年 / 11卷 / 07期
基金：
中国国家自然科学基金;
关键词：
Electrodeposition; Tin based film; Carbon dioxide; Electrocatalytic reduction; Formate; ELECTROCHEMICAL REDUCTION; FORMIC-ACID; CO2; REDUCTION; FARADAIC EFFICIENCY; METAL-ELECTRODES; CURRENT-DENSITY; SN ELECTRODE; IN-SITU; CATALYSTS; SELECTIVITY;
D O I：
10.20964/2016.07.05
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
Sn based film with a thickness of 169 nm has been electrodeposited on copper plate from a choline chloride/ethylene glycol based electrolyte containing SnCl2. Electrochemical reduction of carbon dioxide (CO2) has been studied on the prepared Sn based film electrode in KHCO3 aqueous solution. The electrolysis results show that the faradaic efficiency for producing formate is affected by the time of the electrode exposed to air and the electrolysis potential. We find that the Sn based film can improve the electrocatalytic activity for CO2 reduction. The faradaic efficiency for producing formate on the Sn based film electrode (74.1%) is higher than that on the Cu plate electrode.
引用
收藏
页码：6183 / 6191
页数：9
相关论文
共 50 条
  • [31] Free-standing Stanene for High Selectivity of Formate in Electrocatalytic Carbon Dioxide Reduction Reaction
    Mei, Xuanhao
    Liu, Cong
    Zhang, Dezheng
    Cao, Jing
    Ge, Rile
    Wang, Junhu
    Xu, Weilin
    ADVANCED ENERGY MATERIALS, 2024, 14 (13)
  • [32] Effects of substrate porosity in carbon aerogel supported copper for electrocatalytic carbon dioxide reduction
    Han, Xu
    Wang, Mei
    Le, My Linh
    Bedford, Nicholas M.
    Woehl, Taylor J.
    Thoi, V. Sara
    ELECTROCHIMICA ACTA, 2019, 297 : 545 - 552
  • [33] Electrochemical conversion of carbon dioxide into formate on tin surfaces
    Xiong, Stephanie
    Clark, Rebecca
    Franco, Cristian
    Haan, John
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2019, 258
  • [34] Rapid Selective Electrocatalytic Reduction of Carbon Dioxide to Formate by an Iridium Pincer Catalyst Immobilized on Carbon Nanotube Electrodes
    Kang, Peng
    Zhang, Sheng
    Meyer, Thomas J.
    Brookhart, Maurice
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (33) : 8709 - 8713
  • [35] ELECTROCATALYTIC CARBON-DIOXIDE REDUCTION
    SULLIVAN, BP
    BRUCE, MRM
    OTOOLE, TR
    BOLINGER, CM
    MEGEHEE, E
    THORP, H
    MEYER, TJ
    ACS SYMPOSIUM SERIES, 1988, 363 : 52 - 90
  • [36] Electrocatalytic carbon dioxide reduction in acid
    Li, Junnan
    Kornienko, Nikolay
    CHEM CATALYSIS, 2022, 2 (01): : 29 - 38
  • [37] Selective electrocatalytic reduction of carbon dioxide to oxalate by lead tin oxides with low overpotential
    Cheng, Yingying
    Hou, Pengfei
    Pan, Hui
    Shi, Han
    Kang, Peng
    APPLIED CATALYSIS B-ENVIRONMENTAL, 2020, 272 (272)
  • [38] Copper/Carbon Heterogenous Interfaces for Enhanced Selective Electrocatalytic Reduction of CO2 to Formate
    Du, Juan
    Xin, Yu
    Dong, Minghua
    Yang, Junjuan
    Xu, Qingling
    Liu, Huizhen
    Han, Buxing
    SMALL, 2021, 17 (41)
  • [39] Nitrogen doped tin oxide nanostructured catalysts for selective electrochemical reduction of carbon dioxide to formate
    Qiankun Li
    Zhuo Wang
    Miao Zhang
    Pengfei Hou
    Peng Kang
    Journal of Energy Chemistry , 2017, (05) : 825 - 829
  • [40] Continuous electrochemical reduction of carbon dioxide into formate using a tin cathode: Comparison with lead cathode
    Alvarez-Guerra, Manuel
    Del Castillo, Andres
    Irabien, Angel
    CHEMICAL ENGINEERING RESEARCH & DESIGN, 2014, 92 (04): : 692 - 701
12345