A Mild Palladium-Catalyzed Suzuki Coupling Reaction of Quinoline Carboxylates with Boronic Acids

被引：17

作者：

Li, Wenjie ^{[1
]}

Gao, Joe J. ^{[1
]}

Zhang, Yongda ^{[1
]}

Tang, Wenjun ^{[1
]}

Lee, Heewon ^{[1
]}

Fandrick, Keith R. ^{[1
]}

Lu, Bruce ^{[1
]}

Senanayake, Chris H. ^{[1
]}

机构：

[1] Boehringer Ingelheim Pharmaceut Inc, Ridgefield, CT 06877 USA

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2011年 / 353卷 / 10期

关键词：

monophosphanes; palladium; quinolines; room temperature reaction; Suzuki-Miyaura cross-coupling; ARYL CHLORIDES; ROOM-TEMPERATURE; SUBSTITUTED QUINOLINES; ORGANOBORON COMPOUNDS; ARYLBORONIC ACIDS; FACILE SYNTHESIS; DERIVATIVES; ARENESULFONATES; ELECTROPHILES; CYCLIZATION;

D O I：

10.1002/adsc.201100141

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A palladium-catalyzed cross-coupling between aryl carboxylates and boronic acids has been achieved for the first time by taking advantage of the enhanced reactivity of quinoline 4-carboxylates. Also for the first time a Suzuki coupling reaction via a self-activation of boronic acids without addition of base is described. The reactions proceed under mild conditions (25-65 degrees C) to give excellent yields, and a wide range of functionalities is tolerated.

引用

页码：1671 / 1675

页数：5

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