Synthesis of Substituted 1,3-Oxazines Using Sulfamic Acid as an Efficient and Eco-Friendly Catalyst

被引:4
|
作者
Damodiran, M. [1 ]
Perumal, Paramasivan T. [1 ]
机构
[1] Cent Leather Res Inst, Div Organ Chem, Chennai 600020, Tamil Nadu, India
关键词
ONE-POT SYNTHESIS; MULTICOMPONENT REACTIONS; 3-COMPONENT SYNTHESIS; DOMINO REACTIONS; DERIVATIVES; MINIMYCIN; LIBRARIES;
D O I
10.1002/jhet.489
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Sulfamic acid catalyzed the synthesis of substituted 1,3-oxazines by one-pot three-component reaction of aniline, alkynoates, and formaldehyde in excellent yields. The catalyst possesses distinct advantages shows ease of handling, good yields, cleaner reactions, nonhygroscopic, noncorrosive, and high activity. Sulfamic acid is a green alternative for metal-containing acidic materials, which are toxic and deleterious for human health and environmental protection.
引用
收藏
页码:1386 / 1391
页数:6
相关论文
共 50 条
  • [41] Mg(HSO4)2: an efficient and eco-friendly catalyst for the synthesis of pyrazoles
    Mirjalili, Bi Bi Fatemeh
    Bamoniri, Abdolhamid
    Akbari, Ali
    CHEMIJA, 2012, 23 (03): : 250 - 254
  • [42] BiCl3 – an eco-friendly catalyst for an efficient synthesis of benzoxazoles at room temperature
    Vishvanath D. Patil
    Nagesh R. Sutar
    Ketan P. Patil
    Prathamesh Giddh
    Chemistry of Heterocyclic Compounds, 2015, 51 : 1019 - 1022
  • [43] Isatin Aldazines Synthesis using A Proton Exchanged Algerian Montmorillonite Clay as Acid Eco-friendly Catalyst
    Benlahreche, Boumadiene
    Taleb, Assya
    Lahrech, Mokhtar B.
    Hacini, Salih
    BULLETIN OF CHEMICAL REACTION ENGINEERING AND CATALYSIS, 2019, 14 (03): : 551 - 558
  • [44] AN EXPEDITIOUS SYNTHESIS OF HIGHLY SUBSTITUTED 1,4-DIAZEPINES AND THEIR REARRANGEMENT INTO 2H-1,3-OXAZINES
    BARLUENGA, J
    TOMAS, M
    BALLESTEROS, A
    KONG, JS
    GARCIAGRANDA, S
    AGUIRRE, A
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (03) : 217 - 218
  • [45] An Eco-Friendly and Efficient Synthesis of Benzoylformic Acid and Methyl Benzoylformate from Styrene
    Dai, Zhihong
    Peng, Xinhua
    Dong, Xiongzi
    Shi, Chunjie
    Rong, Yuan
    ASIAN JOURNAL OF CHEMISTRY, 2012, 24 (11) : 4979 - 4985
  • [46] Eco-Friendly Synthesis of 2-Substituted Benzimidazoles Using Air as the Oxidant
    Chen, Guo-Feng
    Shen, Hai-Dong
    Jia, Hui-Ming
    Zhang, Li-Yan
    Kang, Hong-Yan
    Qi, Qing-Qing
    Chen, Bao-Hua
    Cao, Jia-Li
    Li, Ji-Tai
    AUSTRALIAN JOURNAL OF CHEMISTRY, 2013, 66 (02) : 262 - 266
  • [47] Eco-friendly synthesis of 2-substituted benzothiazoles catalyzed by silica sulfuric acid
    Chen, Guo Feng
    Zhang, Li Yan
    Jia, Hui Ming
    Chen, Bao Hua
    Li, Ji Tai
    Wang, Shu Xiang
    Bai, Guo Yi
    RESEARCH ON CHEMICAL INTERMEDIATES, 2013, 39 (05) : 2077 - 2086
  • [48] Eco-friendly synthesis of 2-substituted benzothiazoles catalyzed by silica sulfuric acid
    Guo Feng Chen
    Li Yan Zhang
    Hui Ming Jia
    Bao Hua Chen
    Ji Tai Li
    Shu Xiang Wang
    Guo Yi Bai
    Research on Chemical Intermediates, 2013, 39 : 2077 - 2086
  • [49] Synthesis of Pyranopyrazoles under Eco-friendly Approach by Using Acid Catalysis
    Reddy, Guda Mallikarjuna
    Garcia, Jarem Raul
    JOURNAL OF HETEROCYCLIC CHEMISTRY, 2017, 54 (01) : 89 - 94
  • [50] Eco-friendly synthesis of esters under ultrasound with p-toluenesulfonic acid as catalyst
    Pacheco, Bruna S.
    Nunes, Camila F. P.
    Rockembach, Caroline T.
    Bertelli, Pablo
    Mesko, Marcia F.
    Roesch-Ely, Mariana
    Moura, Sidnei
    Pereira, Claudio M. P.
    GREEN CHEMISTRY LETTERS AND REVIEWS, 2014, 7 (03) : 265 - 270