Novel phthalocyanines bearing 7-oxy-3-(3,5-difluorophenyl)coumarin moieties: Synthesis, characterization, photophysical and photochemical properties

被引：22

作者：

Erdogan, Tolga ^{[1
]}

Bulut, Mustafa ^{[1
]}

Camur, Meryem ^{[2
]}

机构：

[1] Marmara Univ, Dept Chem, TR-34722 Istanbul, Turkey

[2] Kirklareli Univ, Dept Chem, TR-39100 Kirklareli, Turkey

来源：

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY | 2015年 / 300卷

关键词：

Phthalocyanine; Coumarin; Zinc; Indium; Photodegradation; Singlet oxygen; PHOTODYNAMIC THERAPY; ZINC(II) PHTHALOCYANINE; INDIUM PHTHALOCYANINES; SUBSTITUTED GALLIUM; OPTICAL-PROPERTIES; COUMARIN; PHOTOSENSITIZERS; DERIVATIVES;

D O I：

10.1016/j.jphotochem.2014.12.005

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Two novel phthalonitriles,7-(2,3-dicyanophenoxy)-3-(3,5-difluorophenyl) coumarin (2), 7-(3,4-dicyanophenoxy)-3-(3,5-difluorophenyl) coumarin (3), and corresponding zinc(II)-, indium(III) phthalocyanines were prepared. Additionally, photophysical (fluorescence quantum yields and lifetimes), photochemical (singlet oxygen generation and photodegradation under light irradiation) and spectral properties of the resulting peripherally/non-peripherally tetra 7-oxy-3-(3,5-difluorophenyl) coumarin substituted zinc (II) and indium (III) phthalocyanines (4-7) were investigated. All compounds (1-7) were characterized by elemental analysis, IR, H-1 NMR, mass and UV-vis spectral data. The obtained 7-oxy-3-(3,5-difluorophenyl) coumarin bearing pure zinc (II) and indium (III) phthalocyanine complexes were well soluble in organic solvents and displayed good singlet-oxygen generation and appropriate photodegradation. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：6 / 14

页数：9

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