CO2 adsorption properties of a Ca(II)-based organophosphonium coordination material

被引：24
|
作者：
Ibarra, Ilich A. [1 ]
Tan, Kristina E. [1 ]
Lynch, Vincent M. [1 ]
Humphrey, Simon M. [1 ]
机构：
[1] Univ Texas Austin, Dept Chem & Biochem, Austin, TX 78712 USA
来源：
DALTON TRANSACTIONS | 2012年 / 41卷 / 14期
关键词：
METAL-ORGANIC FRAMEWORK; STRUCTURAL-CHARACTERIZATION; HYDROGEN; EXCHANGE; SITES; PORE;
D O I：
10.1039/c2dt12011a
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
PCM-14 is a dense coordination polymer formed from Ca(II) and an unusual organophosphonium ligand. The dehydrated framework contains 3-coordinate Ca(II) sites within catenated, chiral 3,3-connected nets. PCM-14 exhibits a stark CO2 sorption selectivity over H-2, N-2 and O-2. The maximum CO2 uptake was shown to be highly sensitive to the material pretreatment evacuation temperature.
引用
收藏
页码：3920 / 3923
页数：4
相关论文
共 50 条
  • [31] COMPOSITION AND PROPERTIES OF THE ADSORPTION PRODUCTS OF CO AND CO2 ON PLATINIZED PLATINUM
    KAZARINOV, VE
    ANDREEV, VN
    SHLEPAKOV, AV
    ELECTROCHIMICA ACTA, 1989, 34 (07) : 905 - 913
  • [32] The adsorption of CO2 and CO on Ca and CaO films studied with MIES, UPS and XPS
    Voigts, F.
    Bebensee, F.
    Dahle, S.
    Volgmann, K.
    Maus-Friedrichs, W.
    SURFACE SCIENCE, 2009, 603 (01) : 40 - 49
  • [33] Comparative Study of Conventional and Ultrasonic-Assisted Synthesis of Co(II)- and Cu(II)-Based MOFs for CO2 Adsorption
    Ahmadi, Mohammad Reza
    Jamalizadeh, Effat
    Ebrahimipour, S. Yousef
    Sargazi, Ghasem
    APPLIED ORGANOMETALLIC CHEMISTRY, 2025, 39 (04)
  • [34] Synthesis of polymeric ionic liquids material and application in CO2 adsorption
    Ran, Haiying
    Wang, Jiexin
    Abdeltawab, Ahmed A.
    Chen, Xiaochun
    Yu, Guangren
    Yu, Yinghao
    JOURNAL OF ENERGY CHEMISTRY, 2017, 26 (05) : 909 - 918
  • [35] CO2 Adsorption Investigation on an Innovative Nanocomposite Material with Hierarchical Porosity
    Candamano, S.
    Policicchio, A.
    Macario, A.
    Conte, G.
    Agostino, R. G.
    Frontera, P.
    Crea, F.
    JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2019, 19 (06) : 3223 - 3231
  • [36] Synthesis of polymeric ionic liquids material and application in CO2 adsorption
    Haiying Ran
    Jiexin Wang
    Ahmed A.Abdeltawab
    Xiaochun Chen
    Guangren Yu
    Yinghao Yu
    Journal of Energy Chemistry , 2017, (05) : 909 - 918
  • [37] Asymmetric Coordination Induces Electron Localization at Ca Sites for Robust CO2 Electroreduction to CO
    Wang, Qiyou
    Dai, Minyang
    Li, Hongmei
    Lu, Ying-Rui
    Chan, Ting-Shan
    Ma, Chao
    Liu, Kang
    Fu, Junwei
    Liao, Wanru
    Chen, Shanyong
    Pensa, Evangelina
    Wang, Ye
    Zhang, Shiguo
    Sun, Yifei
    Cortes, Emiliano
    Liu, Min
    ADVANCED MATERIALS, 2023, 35 (21)
  • [38] Stepwise growth of melamine-based dendrimers into mesopores and their CO2 adsorption properties
    Liang, Zhijian
    Fadhel, Bandar
    Schneider, Caspar J.
    Chaffee, Alan L.
    MICROPOROUS AND MESOPOROUS MATERIALS, 2008, 111 (1-3) : 536 - 543
  • [39] Preparation and CO2 Adsorption Properties of Porous Particles Based on Alkaline Solid Wastes
    Lu, Wei
    Su, Hao
    Qi, Guansheng
    Zhang, Huilin
    Wang, Mingjun
    Hu, Xiangming
    LANGMUIR, 2022, 38 (37) : 11382 - 11391
  • [40] Preparation and CO2 adsorption properties of tannin modified phenolic based carbon cryogels
    Zhou Y.
    Luo L.
    Fan M.
    Du G.
    Zhao W.
    Fuhe Cailiao Xuebao/Acta Materiae Compositae Sinica, 2023, 40 (01):
12345