Layered structure of catena-poly[[bis[1-(2-azidoethyl)tetrazole-N4]copper(II)]-di-μ-chloro]

被引：22

作者：

Ivashkevich, DO ^{[1
]}

Lyakhov, AS ^{[1
]}

Gaponik, PN ^{[1
]}

Bogatikov, AN ^{[1
]}

Govorova, AA ^{[1
]}

机构：

[1] Belarusian State Univ, Inst Physchem Problems, Minsk 220050, BELARUS

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2001年 / 57卷

关键词：

D O I：

10.1107/S1600536801009965

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, [CuCl2(C3H5N7)(2)], the coordination polyhedron of the Cu atom is an elongated square bipyramid with (1) over bar site symmetry. The equatorial positions are occupied by the two Cl atoms with Cu-Cl distances of 2.288 (1) Angstrom and two azidoethyltetrazole ligands with Cu-N distances of 1.999 (2) Angstrom. Two Cl atoms in axial positions are 2.956 (1) Angstrom distant from the Cu atom. The Cl atoms play the role of nonsymmetrical bridges responsible for formation of layers parallel to the bc plane.

引用

页码：M335 / M337

页数：3

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