Hydroxyl-Rich Deep Eutectic Solvents Assistant Synthesis of VPO and Its Application in Selective Oxidation of n-Butane

被引：22
|
作者：
Shi, Yanan [1 ,2 ]
Dai, Fei [2 ]
Zhang, Ting [2 ]
He, Bin [2 ]
Zhang, Ruirui [2 ]
Liu, Ruixia [1 ,2 ,3 ]
Ren, Baozeng [1 ]
机构：
[1] Zhengzhou Univ, Sch Chem Engn, Zhengzhou 450001, Peoples R China
[2] Chinese Acad Sci, Innovat Acad Green Manufacture, Beijing Key Lab Ion Liquids Clean Proc, Inst Proc Engn, Beijing 100190, Peoples R China
[3] Zhengzhou Inst Emerging Ind Technol, Zhengzhou 450000, Peoples R China
来源：
CHEMISTRYSELECT | 2020年 / 5卷 / 23期
关键词：
Deep eutectic solvents; Maleic anhydride; n-Butane oxidation; Vanadium phosphorus oxide; PHOSPHORUS OXIDE CATALYSTS; VANADIUM PHOSPHATE CATALYSTS; CHOLINE CHLORIDE; ACTIVE PHASE; MALEIC-ANHYDRIDE; PERFORMANCE; SURFACE; NANOSTRUCTURE; PYROPHOSPHATE; MECHANISM;
D O I：
10.1002/slct.202001090
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Deep eutectic solvents (DESs) consisting of choline chloride (ChCl) and polyols (Ethylene glycol (EG), 1,4-Butanediol (BDO), Glycerol (GL), and Xylitol (XYL)) as a green and effective promoter assisting the synthesis of vanadium phosphorus oxide (VPO) were innovatively proposed and investigated in detail for the selective oxidation of n-butane to maleic anhydride (MA). The catalytic results showed that the performance of VPO catalysts was improved significantly with the addition of polyols DESs. A combination of techniques including SEM, TEM, XRD, FT-IR, Raman, XPS, and TG-DTA were employed to investigate the effect of DES on the structure of VPO. We correlated the structure of the catalysts with catalytic performance and found that the n-butane conversion was positively correlated with the intensity ratio of I-(020)/I((204))for catalysts, and the MA selectivity of VPO catalysts was negatively correlated with the vanadium average oxidation state on the catalyst surface.
引用
收藏
页码：6907 / 6917
页数：11
相关论文
共 50 条
  • [31] Fabrication of CdxZn1−xS@VPO (x = 0.2) Nanocomposites for n-Butane Selective Oxidation Toward Maleic Anhydride
    Muhammad Faizan
    Aamir Saeed
    Piao Song
    Ruirui Zhang
    Ruixia Liu
    Zhi Chang
    Liuzhu Wu
    Manyuan Zhang
    Catalysis Letters, 2023, 153 : 3074 - 3091
  • [32] Effect of III B metals (Sc, Y, La and Ce) on active components regulation of VPO catalyst in n-butane selective oxidation
    Li, Wenjiao
    Guo, Shupeng
    Guo, Heqin
    Xiao, Yong
    Jia, Litao
    Li, Debao
    MOLECULAR CATALYSIS, 2023, 547
  • [33] Synthesis of Vanadium Phosphate Catalysts by Hydrothermal Method for Selective Oxidation of n-butane to Maleic Anhydride
    Y. H. Taufiq-Yap
    A. R. Mohd. Hasbi
    M. Z. Hussein
    G. J. Hutchings
    J. Bartley
    N. Dummer
    Catalysis Letters, 2006, 106 : 177 - 181
  • [34] Synthesis of vanadium phosphate catalysts by hydrothermal method for selective oxidation of n-butane to maleic anhydride
    Taufiq-Yap, YH
    Hasbi, ARM
    Hussein, MZ
    Hutchings, GJ
    Bartley, J
    Dummer, N
    CATALYSIS LETTERS, 2006, 106 (3-4) : 177 - 181
  • [35] Quantitative solid-state NMR investigation of V5+ species in VPO catalysts upon sequential selective oxidation of n-butane
    Frey, Joerg
    Lieder, Christian
    Schoelkopf, Thomas
    Schleid, Thomas
    Nieken, Ulrich
    Klemm, Elias
    Hunger, Michael
    JOURNAL OF CATALYSIS, 2010, 272 (01) : 131 - 139
  • [36] Selective oxidation of n-butane on a V-P-O catalyst:: Study under fuel-rich conditions
    Mota, S
    Abon, M
    Volta, JC
    Dalmon, JA
    JOURNAL OF CATALYSIS, 2000, 193 (02) : 308 - 318
  • [37] Mono-, Bi-, and Tri-Metallic DES Are Prepared from Nb, Zr, and Mo for n-Butane Selective Oxidation via VPO Catalyst
    Faizan, Muhammad
    Niazi, Kifayat Ullah Khan
    Nawaz, Hasnain
    Muhammad, Niaz
    Li, Hao
    Dai, Fei
    Zhang, Ruirui
    Liu, Ruixia
    Zhang, Suojiang
    PROCESSES, 2021, 9 (09)
  • [38] Novel Synthesis Techniques for Preparation of Ultrahigh-Crystalline Vanadyl Pyrophosphate as a Highly Selective Catalyst for n-Butane Oxidation
    Rownaghi, Ali Asghar
    Taufiq-Yap, Yun Hin
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2010, 49 (05) : 2135 - 2143
  • [39] Synthesis of CuSCN particles in deep eutectic solvents and its application in the thermal decomposition of ammonium perchlorate
    Lv, Shiqi
    Sui, Lin
    Zeng, Ying
    Cheng, Yun
    Liu, Chunsheng
    Luo, Genxiang
    PARTICULATE SCIENCE AND TECHNOLOGY, 2016, 34 (04) : 407 - 411
  • [40] Synthesis and catalytic activity of vanadium phosphorous oxides systems supported on silicon carbide for the selective oxidation of n-butane to maleic anhydride
    Shcherban, N. D.
    Diyuk, E. A.
    Sydorchuk, V. V.
    REACTION KINETICS MECHANISMS AND CATALYSIS, 2019, 126 (02) : 975 - 985
12345