Synthesis and Crystal Structure of two Cu(II) Complexes with Benzimidazole Ligands

被引：1
|
作者：
Miao, S. B. [1 ,2 ]
Ji, B. M. [1 ]
Du, C. X. [2 ]
机构：
[1] Luoyang Normal Univ, Coll Chem & Chem Engn, Luoyang 471022, Peoples R China
[2] Zhengzhou Univ, Dept Chem, Zhengzhou 450052, Peoples R China
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2011年 / 37卷 / 06期
关键词：
3,3'-BIS(2-BENZIMIDAZOLYL)-2,2'-DIPYRIDINE;
D O I：
10.1134/S1070328411060066
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two new copper(II) complexes (I, II) with benzimidazole ligands have been synthesized and characterized by elemental analysis and X-ray single-crystal diffraction. Compound I is triclinic, P1, a = 11.4205(6), b = 13.0956(7), c = 18.2305(9) angstrom, alpha = 85.960(1)degrees, beta = 80.388(0)degrees, gamma = 77.517(1)degrees, V = 2623.0(2) angstrom(3), Z = 2; compound II is monoclinic, C2/c, a = 24.2684(11), b = 17.5247(8), c = 19.3149(15) angstrom, beta = 122.710(1)degrees, V = 6911.9(7) angstrom(3), Z = 4. In both compounds, Cu(II) atoms are coordinated by four benzimidazole nitrogen atoms in a slightly distorted tetrahedral fashion.
引用
收藏
页码：468 / 472
页数：5
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