Kinetic and stereospecific manifestations of a set of active centres in butadiene polymerization under the action of a catalytic system based on NdCl3•3TBP

被引：0

作者：

Monakov, YB ^{[1
]}

Sabirov, ZM ^{[1
]}

Duvakina, NV ^{[1
]}

Urazbaev, VN ^{[1
]}

Ponomareva, OA ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Organ Chem, Ufa Res Ctr, Ufa 450054, Russia

来源：

MENDELEEV COMMUNICATIONS | 2001年 / 04期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The unusual dependence of butadiene conversion and polymer microstructure on the ratio Mg/Nd or Al/Nd during the polymerization of butadiene under the action of NdCl3. 3TBP-AlBu3i-MgBu(i-C8H17) can be explained by the formation of a set of active centres in the catalytic system.

引用

页码：157 / 159

页数：3

共 37 条

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[34] STUDY OF THE INFLUENCE OF DONOR NATURE ON THE PROCESS OF ALTERNATING THE COPOLYMERIZATION OF BUTADIENE WITH PROPYLENE UNDER THE ACTION OF THE CATALYTIC-SYSTEM TICL4-AL(ISO-C4H9)3
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[35] NATURE OF ACTIVE CENTRES WHEN BUTADIENE-1,3 IS POLYMERIZED IN PRESENCE OF COCL2.PY2-AL(I-C4H9)2CL-H2O CATALYTIC SYSTEM
VOLKOV, LA
MEDVEDEV, SS
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[36] STUDY OF THE DEPENDENCE OF THE RATE OF THE ALTERNATING CO-POLYMERIZATION OF BUTADIENE WITH PROPYLENE UNDER THE INFLUENCE OF THE TICL4-C6H5COCH3-AL(ISO-C4H9)3 CATALYTIC-SYSTEM ON THE MONOMER CONCENTRATIONS
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KINETICS AND CATALYSIS, 1982, 23 (02) : 411 - 413
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VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A, 1981, 23 (10): : 2232 - 2236

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