Kinetic and stereospecific manifestations of a set of active centres in butadiene polymerization under the action of a catalytic system based on NdCl3•3TBP

被引：0
|
作者：
Monakov, YB [1 ]
Sabirov, ZM [1 ]
Duvakina, NV [1 ]
Urazbaev, VN [1 ]
Ponomareva, OA [1 ]
机构：
[1] Russian Acad Sci, Inst Organ Chem, Ufa Res Ctr, Ufa 450054, Russia
来源：
MENDELEEV COMMUNICATIONS | 2001年 / 04期
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中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The unusual dependence of butadiene conversion and polymer microstructure on the ratio Mg/Nd or Al/Nd during the polymerization of butadiene under the action of NdCl3. 3TBP-AlBu3i-MgBu(i-C8H17) can be explained by the formation of a set of active centres in the catalytic system.
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页码：157 / 159
页数：3
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