The synthesis of sulfonated 4H-3,1-benzoxazines via an electro-chemical radical cascade cyclization

被引：42

作者：

He, Tian-Jun ^{[1
]}

Zhong, Wei-Qiang ^{[1
]}

Huang, Jing-Mei ^{[1
]}

机构：

[1] South China Univ Technol, Sch Chem & Chem Engn, Key Lab Funct Mol Engn Guangdong Prov, Guangzhou 510640, Guangdong, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2020年 / 56卷 / 18期

基金：

中国国家自然科学基金;

关键词：

C-H FUNCTIONALIZATION; OLEFINIC AMIDES; CATALYZED ARYLSULFONYLATION; 2-SUBSTITUTED QUINAZOLINES; TANDEM CYCLIZATION; ACTIVATED ALKYNES; ACCESS; ALKENES; 3,4-DIHYDROQUINOLIN-2(1H)-ONES; TRIFLUOROMETHYLATION;

D O I：

10.1039/c9cc09551a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new route for the synthesis of sulfonated 4H-3,1-benzoxazines has been accomplished by electrochemical radical cascade cyclizations of styrenyl amides with sulfonylhydrazines. This process demonstrates a wide substrate scope with diverse functional group compatibility under metal- and external oxidant-free conditions at ambient temperature.

引用

页码：2735 / 2738

页数：4

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