Spodium Bonds: Noncovalent Interactions Involving Group 12 Elements

被引：162

作者：

Bauza, Antonio ^{[1
]}

Alkorta, Ibon ^{[2
]}

Elguero, Jose ^{[2
]}

Mooibroek, Tiddo J. ^{[3
]}

Frontera, Antonio ^{[1
]}

机构：

[1] Univ Illes Balears, Dept Quim, Crta Valldemossa Km 7-5, Palma De Mallorca 07122, Baleares, Spain

[2] Inst Quim Med, Juan Cierva 3, Madrid 28006, Spain

[3] Univ Amsterdam, Vant Hoff Inst Mol Sci, Sci Pk A 904,E1-26, NL-1098 XH Amsterdam, Netherlands

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2020年 / 59卷 / 40期

关键词：

ab initio calculations; donor-acceptor systems; non-covalent bonding; spodium bonds; supramolecular chemistry; DER-WAALS RADII; VAN;

D O I：

10.1002/anie.202007814

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The term spodium (Sp) bond is proposed to refer to a net attractive interaction between any element of Group 12 and electron-rich atoms (Lewis bases or anions). These noncovalent interactions are markedly different from coordination bonds (antibonding Sp-ligand orbital involved). Evidence is provided for the existence of this interaction by calculations at the RI-MP2/aug-cc-pVTZ level of theory, atoms-in-molecules, and natural bond orbital analyses and by examining solid-state structures in the Cambridge Structure Database.

引用

页码：17482 / 17487

页数：6

共 50 条

[1] Erythronium Bonds: Noncovalent Interactions Involving Group 5 Elements as Electron-Density Acceptors
Calabrese, Miriam
Gomila, Rosa M.
Pizzi, Andrea
Frontera, Antonio
Resnati, Giuseppe
CHEMISTRY-A EUROPEAN JOURNAL, 2023, 29 (60)
[2] Spodium and tetrel bonds involving Zn(II)/Cd(II) and their interplay
Liu, Na
Li, Qingzhong
Scheiner, Steve
CHEMICAL PHYSICS, 2022, 556
[3] Spodium Bonding to Dicoordinated Group 12 Atoms
Amonov, Akhtam
Scheiner, Steve
JOURNAL OF PHYSICAL CHEMISTRY A, 2024, 128 (40): : 8751 - 8761
[4] Molecular Electrostatic Potential and Noncovalent Interactions in Derivatives of Group 8 Elements
Daolio, Andrea
Pizzi, Andrea
Calabrese, Miriam
Terraneo, Giancarlo
Bordignon, Simone
Frontera, Antonio
Resnati, Giuseppe
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2021, 60 (38) : 20723 - 20727
[5] Hg(II).d8[M] Interactions: Are they Metallophilic Interactions or Spodium Bonds?
Burguera, Sergi
Bauza, Antonio
Frontera, Antonio
CHEMPHYSCHEM, 2023, 24 (24)
[6] The nature of π-hole spodium bonds in the HgLCl2(L = pyrrole, pyrazole, imidazole, pyridine, pyridazine, and pyrimidine) complexes: from noncovalent to covalent interactions
Tian, Rong
Zeng, Yanli
Li, Xiaoyan
Zhang, Xueying
NEW JOURNAL OF CHEMISTRY, 2024, 48 (15) : 6582 - 6589
[7] Not Only Hydrogen Bonds: Other Noncovalent Interactions
Alkorta, Ibon
Elguero, Jose
Frontera, Antonio
CRYSTALS, 2020, 10 (03)
[8] Noncovalent Interactions Involving Group 6 in Biological Systems: The Case of Molybdopterin and Tungstopterin Cofactors
Bauza, Antonio
Frontera, Antonio
CHEMISTRY-A EUROPEAN JOURNAL, 2022, 28 (50)
[9] Quantitative insights into noncovalent interactions involving halogen and tetrel bonds in 2,4,6-trimethylpyrylium tetrafluoroborate
Mandal, Koushik
Sarkar, Sounak
Ghosh, Peuli
Hathwar, Venkatesha R.
Chopra, Deepak
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2022, 78 : 597 - +
[10] Noncovalent n → π* Interactions in Collagen: The Key for Everlasting Bonds?
Rubini, Marina
ACS CENTRAL SCIENCE, 2024, 10 (10) : 1813 - 1814

← 1 2 3 4 5 →