1-Methyl-3-(4-chlorobenzoyl)imidazo[1,2-a]pyridin-1-ium-2-olate

被引：3
|
作者：
Rybakov, Victor B. [1 ]
Babaev, Eugene V. [1 ]
机构：
[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119992, Russia
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷
基金：
俄罗斯基础研究基金会;
关键词：
HETEROCYCLIC DESIGN; CRYSTAL-STRUCTURE; DIFFRACTION;
D O I：
10.1107/S1600536811039614
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the molecule of the title compound, C15H11ClN2O2, the nine-membered heterobicycle is approximately planar [largest deviation from least-squares plane = 0.012 (2) angstrom] and forms a dihedral angle of 51.14 (8)degrees with the plane of the 4-chlorophenyl group. There is a non-classical intramolecular hydrogen bond between the pyridine alpha-H atom and the O atom of the benzoyl group. The crystal structure is stabilized by weak C-H center dot center dot center dot O and C-H center dot center dot center dot Cl interactions involving the 'olate' O atom and the Cl atom attached to the benzoyl group as acceptors.
引用
收藏
页码：O2814 / +
页数：10
相关论文
共 50 条
  • [21] The crystal structure of (E)-4-(2-(pyridin-4-ylmethylene)hydrazine-1-carbonyl)pyridin-1-ium-2-olate dihydrate, C12H14N4O4
    Zhao, Zeng-Bing
    Cheng, Lan-Xing
    Yang, Shu-Cheng
    Chai, Yong-Li
    Tai, Xi-Shi
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2024, 239 (05): : 975 - 977
  • [22] Synthesis and properties of imidazo[1,2-a]pyridinium-3-olate. Some revised structures
    Lindner, Anika Sabine
    Nieger, Martin
    Schmidt, Andreas
    TETRAHEDRON, 2009, 65 (36) : 7591 - 7596
  • [23] 1-[(4-chlorobenzoyl)methyl]-4,6-dimethyl-2(1H)-pyrimidone
    Rybakov, Victor B.
    Alifanov, Vadim L.
    Gormay, Pavel V.
    Babaev, Eugene V.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : O3840 - O3841
  • [24] Zwitterionic 3-carboxylatomethyl-3-carboxymethyl-2-oxo-2,3-dihydroimidazo[1,2-a]pyridin-1-ium
    Qiao, Shu
    Yong, Guo-Ping
    Xie, Yu
    Wang, Zhi-Yong
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : O4634 - O4635
  • [25] NEW TRICYCLIC COMPOUNDS - PYRIDO[2',3'-4,5]IMIDAZO[1,2-A]PYRIMIDINES AND PYRIDO[3',2'-4,5]IMIDAZO[1,2-A]PYRIMIDINES
    DESCOURS, D
    FESTAL, D
    HETEROCYCLES, 1990, 31 (02) : 259 - 265
  • [26] Nanoarchitectonics and Molecular Docking of 4-(Dimethylamino)Pyridin-1-Ium 2-3 Methyl-4-Oxo-Pyri-Do[1,2-a]Pyrimidine-3-Carboxylate
    Lahmidi, Sanae
    Anouar, El Hassane
    Ettahiri, Walid
    El Hafi, Mohamed
    Lazrak, Fatima
    Alanazi, Mohammed M.
    Alanazi, Ashwag S.
    Hefnawy, Mohamed
    Essassi, El Mokhtar
    Mague, Joel T.
    CRYSTALS, 2023, 13 (09)
  • [27] 1-methyl-2-(4-nitrophenyl)imidazo[1,2-a]pyridinium perchlorate:: a powder study
    Rybakov, Victor B.
    Babaev, Eugene V.
    Sonneveld, Eduard J.
    Zhukov, Sergei G.
    Chernyshev, Vladimir V.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 : O1861 - O1863
  • [28] Crystal structure of zwitterionic 3-(2-hydroxy-2-phosphonato-2-phosphonoethyl)imidazo[1,2-a]-pyridin-1-ium monohydrate (minodronic acid monohydrate): a redetermination
    Airoldi, Annalisa
    Bettoni, Piergiorgio
    Donnola, Monica
    Calestani, Gianluca
    Rizzoli, Corrado
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : 51 - +
  • [29] IMIDAZO[1,2-A]PYRIDINES .2. OZONOLYSIS OF IMIDAZO[1,2-A]PYRIDINES AND SYNTHESIS OF CARDIOTONIC AGENTS
    YAMANAKA, M
    SUDA, S
    YONEDA, N
    OHHARA, H
    CHEMICAL & PHARMACEUTICAL BULLETIN, 1992, 40 (03) : 666 - 674
  • [30] 2-Methyl-3-(1H-pyrazol-3-yl)imidazo-[1,2-a]pyrimidine
    Gao, Guo-Rui
    Duan, Wen-Hu
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O1977 - +
12345