{2,2′-[(2,2-Dimethylpropane-1,3-diyldinitrilo)bis(phenylmethylidyne)]diphenolato}copper(II)

被引:2
|
作者
Kargar, Hadi [1 ]
Kia, Reza [2 ,3 ]
Moghadam, Majid [4 ]
Froozandeh, Fatemeh [1 ]
Tahir, Muhammad Nawaz [5 ]
机构
[1] Payame Noor Univ, Dept Chem, Tehran 193954697, Iran
[2] Islamic Azad Univ, Xray Crystallog Lab, Plasma Phys Res Ctr, Sci & Res Branch, Tehran, Iran
[3] Islamic Azad Univ, Sci & Res Branch, Dept Chem, Tehran, Iran
[4] Univ Isfahan, Catalysis Div, Dept Chem, Esfahan 8174673441, Iran
[5] Univ Sargodha, Dept Phys, Punjab, Pakistan
关键词
data-to-parameter ratio = 14.4; mean σ(CC) = 0.008 Å; R factor = 0.070; single-crystal X-ray study; T = 291 K; wR factor = 0.064;
D O I
10.1107/S1600536811028844
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The complete molecule of the title complex, [Cu(C31H28N2O2)], is generated by the application of twofold symmetry; the Cu and CMe2 atoms lie on the axis. The geometry around the Cu-II atom is distorted square-planar. The dihedral angle between the two phenyl rings is 76.0 (3)degrees. The crystal packing is stabilized by intermolecular C-H center dot center dot center dot pi interactions.
引用
收藏
页码:M1145 / U1259
页数:9
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