Electron beam-based functionalization of polymer membranes

被引：32
|
作者：
Schulze, A. [1 ]
Marquardt, B. [1 ]
Went, M. [1 ]
Prager, A. [1 ]
Buchmeiser, M. R. [2 ]
机构：
[1] Leibniz Inst Oberflachenmodifizierung eV, D-04318 Leipzig, Germany
[2] Univ Stuttgart, Inst Polymerchem, D-70550 Stuttgart, Germany
来源：
WATER SCIENCE AND TECHNOLOGY | 2012年 / 65卷 / 03期
关键词：
electron beam irradiation; fouling; protein adsorption; surface modification; water wettability;
D O I：
10.2166/wst.2012.890
中图分类号：
X [环境科学、安全科学];
学科分类号：
08 ; 0830 ;
摘要：
A new electron beam-based approach for the direct functionalization of polyethersulfone, polyvinylidene fluoride, polysulfone as well as polyacrylonitrile membranes in a one-step procedure is presented. Aqueous solutions of functional molecules were immobilized on the membrane surface by electron beam treatment. The resulting membranes show significantly increased flux and water wettability accompanied by decreased protein adsorption. Stability tests demonstrated the permanence of the modification. This new method neither requires any preceding surface functionalization nor the use of catalysts/photoinitiators or other toxic reagents. In addition, it avoids the synthesis of hydrophilic monomers/polymers, thus avoiding additional synthetic and purification steps as well as the use of organic solvents.
引用
收藏
页码：574 / 580
页数：7
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