Secondary phosphine oxides: Versatile ligands in transition metal-catalyzed cross-coupling reactions

被引：174

作者：

Shaikh, Tanveer Mahamadali ^{[1
]}

Weng, Chia-Ming ^{[1
]}

Hong, Fung-E ^{[1
]}

机构：

[1] Natl Chung Hsing Univ, Dept Chem, Taichung 40227, Taiwan

来源：

COORDINATION CHEMISTRY REVIEWS | 2012年 / 256卷 / 9-10期

关键词：

Secondary phosphine oxide (SPO); Cross-coupling; SPO in asymmetric reactions; Density functional theory (DFT); Palladium; CARBON-CARBON BOND; CHIROGENIC DIAMINOPHOSPHINE OXIDES; ASYMMETRIC ALLYLIC AMINATION; PREPARING AROMATIC KETONES; ARYL GRIGNARD-REAGENTS; HIGHLY-ACTIVE CATALYST; SUZUKI-MIYAURA TYPE; ACYL CHLORIDES; ACID-CHLORIDES; ARYLBORONIC ACIDS;

D O I：

10.1016/j.ccr.2011.11.007

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This review describes the development in the use of secondary phosphine oxides ligands in transition-metal-catalyzed oxidative coupling reactions to the formation of C-C, C-N and C-S bonds. Also the developments in the recent literature are highlighted in the areas of cycloaddition, coupling of acyl halide with organometallic reagents, oxidations and other reactions. The secondary phosphine oxides are known to exist in the tautomeric forms and are configurationally stable; this property enables a variety of useful transformations for accessing optically active organophosphorus compounds which are useful in the formation of C-C bonds and asymmetric hydrogenation reactions. Finally, the mechanistic aspect employing DFT technique in these oxidative coupling reactions is described in this article. (C) 2011 Elsevier B.V. All rights reserved.

引用

页码：771 / 803

页数：33

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