Boronic acids in the design and synthesis of supramolecular assemblies

被引:106
|
作者
Pedireddi, VR [1 ]
Seethalekshmi, N [1 ]
机构
[1] Natl Chem Lab, Div Organ Chem, Pune 411008, Maharashtra, India
关键词
boronic acids; O-H center dot center dot center dot N hydrogen bonds; supramolecular synthesis; C-H center dot center dot center dot pi interactions; molecular recognition;
D O I
10.1016/j.tetlet.2004.01.005
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Supramolecular assemblies of phenylboronic and 4-methoxyphenylboronic acids with 4,4'-bipyridine and an assembly of phenylboronic acid with 1,2-bis(4-pyridyl)ethene, which were obtained due to the formation of O-H...N hydrogen bonds between hetero N-atoms and -B(OH)(2) are reported. Further, a centrosymmetric cyclic C-H...O hydrogen bonding dimer is identified in the crystal structure of 4-methoxyphenylboronic acid. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1903 / 1906
页数:4
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