Aryloxide anions can form outer sphere complexes with metals as electropositive as uranium

被引：6

作者：

Evans, William J. ^{[1
]}

Walensky, Justin R. ^{[1
]}

Ziller, Joseph W. ^{[1
]}

机构：

[1] Univ Calif Irvine, Dept Chem, Irvine, CA 92697 USA

来源：

CHEMICAL COMMUNICATIONS | 2009年 / 47期

关键词：

ACTINIDE ENVIRONMENTAL CHEMISTRY; NEUTRON-DIFFRACTION; MOLECULAR-STRUCTURE; MONOCLINIC FORM; DYNAMICS; BONDS; SPECIATION; INSERTION; CRYSTAL; ION;

D O I：

10.1039/b912222b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A uranium complex containing an outer sphere aryloxide anion is formed by the proteolytic cleavage of the methyl group in the mono-methyl uranium metallocene, (C(5)Me(5))(2)[(i)PrNC(Me)N(i)Pr]UMe, by 2,6-di-tert-butyl-4-methyl phenol.

引用

页码：7342 / 7344

页数：3

共 28 条

[21] OUTER-SPHERE COMPLEXES OF TRIS (1,10-PHENANTHROLINE)-IRON(II) AND TRIS(2,2'-BIPYRIDINE)IRON(II) IONS WITH SEVERAL ANIONS
JOHANSSON, L
CHEMICA SCRIPTA, 1976, 10 (02): : 72 - 75
[22] INVESTIGATIONS ON OUTER-SPHERE COMPLEXES OF TRIS-(ETHYLENEDIAMINE)-COBALT(III) AND HEXAMINE-COBALT(III) - CATIONS FORMED WITH ORTHO-PHOSPHATE AND PYROPHOSPHATE ANIONS
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[23] Two new Cu(II) and Ni(II) 1,10-phenanthroline complexes with anions of barbituric acids in the outer sphere: Synthesis, structure, spectroscopic, magnetic and thermal properties
Golovnev, Nicolay N.
Molokeev, Maxim S.
Sterkhova, Irina, V
Lesnikov, Maxim K.
Demina, Anastasia, V
Patrin, Gennady S.
JOURNAL OF MOLECULAR STRUCTURE, 2020, 1219 (1219)
[24] INDUCED OPTICAL-ACTIVITY IN CO(NH3)-6(3+) BY ASSOCIATION WITH CHIRAL ANIONS .2. TENTATIVE SECTOR RULE FOR OUTER-SPHERE COMPLEXES
NORDEN, B
CHEMICA SCRIPTA, 1975, 7 (01): : 14 - 20
[25] OUTER-SPHERE OXIDATION .2. PULSE-RADIOLYSIS STUDY OF THE RATES OF REACTION OF THE I-2-. AND (SCN)2-. RADICAL-ANIONS WITH THE TRIS(2,2'-BIPYRIDYL)2 COMPLEXES OF OS(II) AND OS(III)
NORD, G
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FLORYANLOVBORG, E
PAGSBERG, P
INORGANIC CHEMISTRY, 1982, 21 (06) : 2327 - 2330
[26] NH NMR Shifts of New Structurally Characterized fac-[Re(CO)3(polyamine)]n+ Complexes Probed via Outer-Sphere Hydrogen-Bonding Interactions to Anions, Including the Paramagnetic [ReIVBr6]2- Anion
Perera, Theshini
Marzilli, Patricia A.
Fronczek, Frank R.
Marzilli, Luigi G.
INORGANIC CHEMISTRY, 2010, 49 (12) : 5560 - 5572
[27] Complexes of Np(VI) with Cyclobutanecarboxylic Acid Anions and Single-Charged Cations in the Outer Sphere: [NH4][NpO2(cbc)3], [C(NH2)3][NpO2(cbc)3], and [N(CH3)4][NpO2(cbc)3]
I. A. Charushnikova
M. S. Grigor’ev
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Radiochemistry, 2019, 61 : 420 - 426
[28] Complexes of Np(VI) with Cyclobutanecarboxylic Acid Anions and Single-Charged Cations in the Outer Sphere: [NH4][NpO2(cbc)3], [C(NH2)3][NpO2(cbc)3], and [N(CH3)4][NpO2(cbc)3]
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RADIOCHEMISTRY, 2019, 61 (04) : 420 - 426

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