Aryloxide anions can form outer sphere complexes with metals as electropositive as uranium

被引：6
|
作者：
Evans, William J. [1 ]
Walensky, Justin R. [1 ]
Ziller, Joseph W. [1 ]
机构：
[1] Univ Calif Irvine, Dept Chem, Irvine, CA 92697 USA
来源：
CHEMICAL COMMUNICATIONS | 2009年 / 47期
关键词：
ACTINIDE ENVIRONMENTAL CHEMISTRY; NEUTRON-DIFFRACTION; MOLECULAR-STRUCTURE; MONOCLINIC FORM; DYNAMICS; BONDS; SPECIATION; INSERTION; CRYSTAL; ION;
D O I：
10.1039/b912222b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A uranium complex containing an outer sphere aryloxide anion is formed by the proteolytic cleavage of the methyl group in the mono-methyl uranium metallocene, (C(5)Me(5))(2)[(i)PrNC(Me)N(i)Pr]UMe, by 2,6-di-tert-butyl-4-methyl phenol.
引用
收藏
页码：7342 / 7344
页数：3
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