Vanadium(V) Complexes with Bromo-Substituted Hydrazones: Synthesis, Characterization, X-ray Crystal Structures and Antimicrobial Activity

被引：10
|
作者：
Zhang, Cui-Lin [1 ]
Qiu, Xiao-Yang [1 ,2 ]
Liu, Shu-Juan [1 ]
机构：
[1] Ningbo Univ, Coll Sci & Technol, Ningbo 315212, Zhejiang, Peoples R China
[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
来源：
ACTA CHIMICA SLOVENICA | 2019年 / 66卷 / 03期
关键词：
Vanadium complex; hydrazone; crystal structure; mononuclear complex; antimicrobial activity; OXIDOVANADIUM(V) COMPLEXES; ANTIBACTERIAL ACTIVITY; CATALYTIC-PROPERTY; SCHIFF-BASES; LIGANDS; DESIGN;
D O I：
10.17344/acsi.2019.5241
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Two new V-V complexes with the bromo-substituted hydrazones N'-(3-bromo-2-hydroxybenzylidene)-3-hydroxy- 4-methoxybenzohydrazide (H2L1), N'-(3-bromo-2-hydroxybenzylidene)-3,5-dimethoxybenzohydrazide (H2L2), [VOL1(OCH3)(CH3OH)] (1) and [VOL2(OCH3)(CH3OH)] (2), were synthesized and structurally characterized by IR, UV-Vis and H-1 NMR spectroscopy, as well as single-crystal X-ray determination. The V atom in the mononuclear complexes are six-coordinated in octahedral geometry. The free hydrazones and the complexes were studied on their antibacterial activity on S. aureus, B. subtilis, E. coli and P. fluorescence, and antifungal activity on C. albicans and A. niger. The bromo groups of the hydrazone ligands may increase their antibacterial activity.
引用
收藏
页码：719 / 725
页数：7
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