The first enantioselective total synthesis of (-)-arisugacin A

被引：23

作者：

Cole, KP ^{[1
]}

Hsung, RP ^{[1
]}

机构：

[1] Univ Minnesota, Dept Chem, Minneapolis, MN 55455 USA

来源：

TETRAHEDRON LETTERS | 2002年 / 43卷 / 48期

基金：

美国国家卫生研究院;

关键词：

D O I：

10.1016/S0040-4039(02)02094-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The first enantioselective synthesis of (-)-arisugacin A in 17 steps is described here, featuring a CBS asymmetric ketone reduction and a highly stereoselective formal [3+3] cycloaddition approach. This concise synthesis of the enantiomer unambiguously confirms the original assignment of the absolute configuration. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：8791 / 8793

页数：3

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