Bis[2-amino-6-methylpyrimidin-4(1H)-one-κ2N3,O]dichloridocadmium(II)

被引:5
|
作者
Kaabi, Kamel [1 ]
El Glaoui, Meher [1 ]
Silva, P. S. Pereira [2 ]
Silva, M. Ramos [2 ]
Ben Nasr, Cherif [1 ]
机构
[1] Fac Sci Bizerte, Lab Chim Mat, Zarzouna 7021, Tunisia
[2] Univ Coimbra, Dept Phys, CEMDRX, P-3004516 Coimbra, Portugal
关键词
D O I
10.1107/S1600536810035051
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, [CdCl2(C5H7N3O)(2)], the Cd (II) atom is six- coordinated by two heterocyclic N atoms [Cd-N = 2.261 (2) and 2.286 (2) angstrom] and two O atoms [Cd-O = 2.624 (2) and 2.692 (2) angstrom] from two bidentate chelate 2-amino-6-methylpyrimidin- 4(1H)-one ligands and two chloride ions [Cd-Cl = 2.4674 (6) and 2.4893 (7) angstrom]. The crystal packing is characterized by an open- framework architecture with the crystal packing stabilized by intermolecular N-H center dot center dot center dot Cl and N-H center dot center dot center dot O hydrogen bonds.
引用
收藏
页码:M1225 / U538
页数:11
相关论文
共 50 条
  • [21] cis-Aquadichlorido[pyrimidin-2(1H)-one-κN3]copper(II)
    Kurawa, Mukhtar A.
    Adams, Christopher J.
    Orpen, A. Guy
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : M969 - U1010
  • [22] Bis(2-amino-4-methyl-1,3-thiazole-kN3)dichloridocadmium(II)
    Zhang, Lai-Jun
    Shen, Xing-Can
    Liang, Hong
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : M1248 - U320
  • [23] Bis(2-amino-4-methylpyrimidin-1-ium)hexaaquacobalt(II) disulfate dihydrate
    Mirzaei, M.
    Eshtiagh-Hosseini, H.
    Zarghami, S.
    Karrabi, Z.
    Saeedi, M.
    Mague, J. T.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : M128 - +
  • [24] Bis[μ-2,2′-dimethyl-1,1′-(3-oxapentane-1,5-diyl)di-1H-benzimidazole-κ2N3:N3′]bis[bis(4-methoxybenzoato)-κO;κ2O,O′-cobalt(II)]
    Zhao, Lian-Peng
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : M1549 - U650
  • [25] Bis[(1-methyl-1H-benzimidazol-2-yl)methanol-κ2N3,O]bis(thiocyanato-κN)cobalt(II) methanol solvate
    Zhou, Yan-Ling
    Liang, Hong
    Zeng, Ming-Hua
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : M189 - U963
  • [26] Bis[2-(4,5-dihydro-1H-imidazol-2-yl)phenolato-κ2N3,O]zinc(II) methanol solvate
    He, Hong-Shan
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 : M344 - M345
  • [27] Bis[2-(1H-benzimidazol-2-yl)phenolato-κ2N3,O]cobalt(II) dimethylformamide disolvate
    He, Feigang
    Xi, Yun
    Li, Jun
    Zhang, Fengxing
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : M1311 - U2870
  • [28] Crystal structure, Hirshfeld surface analysis and physicochemical studies of two new Cu(II) complexes with the ligand 2-amino-6-methylpyrimidin-4-(1H)-one
    Boubakri, Rim
    Jelsch, Christian
    Lefebvre, Frederic
    Kaminsky, Werner
    Ben Nasr, Cherif
    Kaabi, Kamel
    INORGANICA CHIMICA ACTA, 2020, 502
  • [29] catena-poly[[dichlorocadmium(II)]bis[μ-1,3-bis(imidazol-1-ylmethyl)benzene-κ2N3:κ2N3′]]
    Li, Tao
    Du, Shao-Wu
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2006, 62 : M1933 - M1935
  • [30] catena-poly[[[μ-1,4-bis(imidazol-1-yl-methyl)benzene-κ2N3:N3′N3']bis[dichlorocopper(II)]]-bis[μ-1,4-bis-(imidazol-1-ylmethyl)benzene]-1:1′κ2N3:N3;2:2′κ2N3:N3′]
    Li, T
    Hu, SM
    Du, SW
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2005, 61 : M409 - M411