New phosphine-imine ligands derived from D-gluco- and D-galactosamine in Pd-catalysed asymmetric allylic alkylation

被引：8
|
作者：
Szulc, Izabela [1 ]
Kolodziuk, Robert [1 ]
Kryczka, Boguslaw [1 ]
Zawisza, Anna [1 ]
机构：
[1] Univ Lodz, Dept Organ & Appl Chem, PL-91403 Lodz, Poland
来源：
TETRAHEDRON LETTERS | 2015年 / 56卷 / 33期
关键词：
D-Glucosamine; D-Galactosamine; Iminophosphine; Homogeneous catalysis; Asymmetric alkylation; Palladium; D-GLUCOSAMINE; SUBSTITUTION-REACTIONS; OXAZOLINE LIGANDS; COMPLEXES; ENANTIOSELECTIVITY;
D O I：
10.1016/j.tetlet.2015.06.031
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
New phosphine-imine chiral ligands which were easily prepared from D-gluco- and D-galactosamine furnished a high level of enantiomeric excess (up to 99%) in the Pd(0)-catalysed asymmetric allylic alkylation of racemic 1,3-diphenyl-2-propenyl acetate with malonates. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码：4740 / 4743
页数：4
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