Palladium-catalysed asymmetric allylic alkylation using new chiral phosphinite-nitrogen ligands derived from D-glucosamine

被引：82
|
作者：
Yonehara, K [1 ]
Hashizume, T [1 ]
Mori, K [1 ]
Ohe, K [1 ]
Uemura, S [1 ]
机构：
[1] Kyoto Univ, Grad Sch Engn, Dept Energy & Hydrocarbon Chem, Sakyo Ku, Kyoto 6068501, Japan
来源：
CHEMICAL COMMUNICATIONS | 1999年 / 05期
关键词：
D O I：
10.1039/a810041a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Novel phosphinite-nitrogen chiral ligands synthesized from D-glucosamine furnish a high level of enantiomeric excess (up to 96% ee) in palladium-catalysed allylic alkylation.
引用
收藏
页码：415 / 416
页数：2
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