Tautomerism and 1H and 13C NMR assignment of methyl derivatives of 9-hydroxyphenalenone

被引：1
|
作者：
Honeyman, B
Spalding, C
Jensen, D
Haddon, RC
机构：
[1] Augustana Coll, Dept Chem, Rock Isl, IL 61021 USA
[2] Univ Calif Riverside, Dept Chem, Riverside, CA 92521 USA
[3] Univ Calif Riverside, Dept Environm Chem & Engn, Riverside, CA 92521 USA
来源：
MAGNETIC RESONANCE IN CHEMISTRY | 2005年 / 43卷 / 12期
关键词：
NMR; H-1; C-13; chemical shifts; 9-hydroxyphenalenone;
D O I：
10.1002/mrc.1706
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
9-Hydroxyphenalenone is a planar multicyclic beta-keto-enol that demonstrates C-2v symmetry on the NMR timescale. Off-axis substitution breaks the molecular symmetry and results in tautomers. H-1 and C-13 NMR assignments were made for 9-hydroxyphenalenone and three methyl derivatives, and the solution-phase tautomers were determined. Copyright (c) 2005 John Wiley & Sons, Ltd.
引用
收藏
页码：1053 / 1056
页数：4
相关论文
共 50 条
  • [21] 1H and 13C NMR of bioactive isochromanylacetylarylhydrazone derivatives
    Santos, MRL
    de Carvalho, MG
    Braz-Filho, R
    Barreiro, EJ
    MAGNETIC RESONANCE IN CHEMISTRY, 1998, 36 (07) : 533 - 538
  • [22] Complete assignment of 1H and 13C NMR spectra of vinflunine
    Ribet, JP
    Zalavari, P
    Fahy, J
    Duflos, A
    Beltran, T
    MAGNETIC RESONANCE IN CHEMISTRY, 2001, 39 (01) : 43 - 48
  • [23] 1H and 13C NMR signal assignment of synthetic (-)-methyl thyrsiflorin B acetate, (-)-thyrsiflorin C and several scopadulane derivatives
    González, MA
    Zaragozá, RJ
    MAGNETIC RESONANCE IN CHEMISTRY, 2005, 43 (10) : 877 - 880
  • [24] Comprehensive 1H and 13C NMR assignment of 13 protobassic acid saponins
    Chen, Hsin-Yi
    Tsai, Sheng-Fa
    Lee, Shoei-Sheng
    JOURNAL OF THE CHINESE CHEMICAL SOCIETY, 2020, 67 (06) : 1089 - 1099
  • [25] Synthesis and complete assignment of the 1H and 13C NMR signals of new acetamido and aminoflavonoid derivatives
    Casano, Gilles
    Robin, Maxime
    Barbier, Pascale
    Peyrot, Vincent
    Faure, Robert
    MAGNETIC RESONANCE IN CHEMISTRY, 2010, 48 (09) : 738 - 744
  • [26] Complete 1H and 13C NMR spectral assignment of α- and β-adenosine, 2'-deoxyadenosine and their acetate derivatives
    Ciuffreda, P.
    Casatii, S.
    Manzocchi, A.
    MAGNETIC RESONANCE IN CHEMISTRY, 2007, 45 (09) : 781 - 784
  • [27] Synthesis and complete assignment of the 1H and 13C NMR signals of some oxopyrancoumarin and oxofuropyrancoumarin derivatives
    Quezada, Elias
    Delogu, Giovanna
    Vina, Dolores
    Santana, Lourdes
    Picciau, Carmen
    Podda, Gianni
    Uriarte, Eugenio
    MAGNETIC RESONANCE IN CHEMISTRY, 2008, 46 (07) : 701 - 705
  • [28] Spectral assignments and reference data -: 1H and 13C NMR spectral assignment of androstane derivatives
    Fuente, A
    Reyes, M
    Alvarez, YM
    Ruiz, JA
    Vélez, H
    Viñas-Bravo, O
    Montiel-Smith, S
    Meza-Reyes, S
    Sandoval-Ramírez, J
    MAGNETIC RESONANCE IN CHEMISTRY, 2005, 43 (08) : 676 - 678
  • [29] Isolation and 1H, 13C NMR assignments for methyl sartortuoate
    Lan, WJ
    Su, JY
    Zeng, LM
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2005, 25 (11) : 1465 - 1468
  • [30] 1H, 13C and 15N NMR spectroscopy and tautomerism of nitrobenzotriazoles
    Larina, Lyudmila I.
    Milata, Viktor
    MAGNETIC RESONANCE IN CHEMISTRY, 2009, 47 (02) : 142 - 148
12345