Preparation and characterization of polypyrrole-coated nanosized novel ceramics

被引:147
|
作者
Cho, GJ [1 ]
Fung, BM
Glatzhofer, DT
Lee, JS
Shul, YG
机构
[1] Sunchon Natl Univ, Dept Chem Engn, Sunchon 540742, Cheon Nam, South Korea
[2] Univ Oklahoma, Dept Chem & Biochem, Norman, OK 73019 USA
[3] Yonsei Univ, Dept Chem Engn, Seoul 1202749, South Korea
[4] K JIST, Kwangju Inst Sci & Technol, Dept Mat Sci & Engn, Kwangju 500712, South Korea
关键词
D O I
10.1021/la0012485
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Surfactant bilayers adsorbed on TS-l zeolite were used as templates to produce colloidal nanocomposites with a polypyrrole(Ppy) shell. The adsorbed surfactant was cetylpyridinium chloride, and it plays a critical role for attaining both the colloidal stability of the nanocomposites and an enhanced conductivity of the Ppy sheath on the TS-1 core. The observed contact conductivity of the nanocomposites was 5 S/cm for a sample with 8 wt % of Ppy incorporation while bulk Ppy powder had a contact conductivity of 0.03 S/cm.
引用
收藏
页码:456 / 461
页数:6
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