Predicting phase equilibria in one-component systems

被引：2
|
作者：
Korchuganova, M. R. [1 ]
Esina, Z. N. [1 ]
机构：
[1] Kemerovo State Univ, Kemerovo 650043, Russia
来源：
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A | 2015年 / 89卷 / 07期
关键词：
one-component system; thermodynamic similarity; vaporization curve; melting curve; sublimation curve; enthalpy of vaporization; enthalpy of melting; enthalpy of sublimation; Simon equation parameters; N-ALKANE MIXTURES; HIGH-PRESSURE; PART; VAPORIZATION; ENTHALPY; LIQUID; BEHAVIOR; EQUATION;
D O I：
10.1134/S0036024415070183
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
It is shown that Simon equation coefficients for n-alkanes and n-alcohols can be modeled using critical and triple point parameters. Predictions of the phase liquid-vapor, solid-vapor, and liquid-solid equilibria in one-component systems are based on the Clausius-Clapeyron relation, Van der Waals and Simon equations, and the principle of thermodynamic similarity.
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页码：1135 / 1140
页数：6
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