Pd nanoparticles supported on Fe3O4@C: An effective heterogeneous catalyst for the transfer hydrogenation of nitro compounds into amines

Catalytic reduction of nitro compounds to the amines is of high importance in modern synthetic chemistry. In this study, an efficient method was developed for the transfer hydrogenation of nitro compounds over a magnetic Pd catalyst by the use of NaBH4 as the hydrogen donor. Full nitrobenzene conversion and high selectivity (>99%) of aniline were produced after 1 h at 60 degrees C in ethanol. The reductions are successfully carried out in presence of a wide variety of other reducible functional groups in the molecule, except halogen and vinyl substitute nitrobenzene. Kinetic studies indicated the active energy for the transfer hydrogenation of nitrobenzene was 20.93 KJ mol(-1). The transfer hydrogenation of nitrobenzene was confirmed to proceed via azobenzene as the intermediate. More importantly, the catalyst was very stable without the loss of its catalytic activity. (C) 2016 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.