Production of 5-(chloromethyl)furan-2-carbonyl chloride and furan-2,5-dicarbonyl chloride from biomass-derived 5-(chloromethyl)furfural (CMF)

被引：0

作者：

Dutta, Saikat ^{[1
]}

Wu, Linglin ^{[1
]}

Mascal, Mark ^{[1
]}

机构：

[1] Univ Calif Davis, Dept Chem, Davis, CA 95616 USA

来源：

GREEN CHEMISTRY | 2015年 / 17卷 / 07期

关键词：

CONVERSION;

D O I：

10.1039/c5gc00936g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Acid chloride derivatives of 5-(chloromethyl) furan-2-carboxylic acid and furan-2,5-dicarboxylic acid (FDCA) can be produced in high yield by treatment of the precursor aldehydes 5-(chloromethyl) furfural (CMF) and 2,5-diformylfuran (DFF) with tert-butyl hypochlorite, which is inexpensively prepared from commercial bleach and tert-butanol. 5-(Chloromethyl) furan-2-carbonyl chloride (CMFCC) and furan-2,5-dicarbonyl chloride (FDCC) are highly useful intermediates for the production of furoate ester biofuels and polymers of FDCA.

引用

页码：3737 / 3739

页数：3

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