Grafting of regenerated cellulose membrane by surface-initiated atom transfer radical polymerization and its pH-resposive behavior

被引:13
|
作者
Pan, Kai [1 ]
Zhang, Xiaowei [1 ]
Zhu, Jie [1 ]
Cao, Bing [1 ]
机构
[1] Beijing Univ Chem Technol, Coll Mat Sci & Engn, Beijing 100029, Peoples R China
基金
中国国家自然科学基金;
关键词
regenerated cellulose membrane; atom transfer radical polymerization ( ATRP); pH modulated permeability properties; poly(acrylic acid); REVERSE-OSMOSIS MEMBRANES; ULTRAFILTRATION MEMBRANES; PERFORMANCE; ATRP;
D O I
10.1002/pat.1699
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Regenerated cellulose (RC) membranes which have pH modulated permeability have been prepared by anchoring the hydroxyl groups on the membrane surface with 2-bromoisobutyryl bromide, followed by grafting with acrylic acid (AA) using atom transfer radical polymerization (ATRP). The obtained membranes were analyzed by X-ray photoelectron spectroscopy (XPS), Fourier transform infrared attenuated total reflection spectrometer (ATR-FTIR), scanning electron microscopy (SEM), TGA and the results showed that AA had been grafted onto the membrane surfaces successfully. Then the pH modulated permeability properties were tested by water flux measurement. All results show that the pH modulated permeability properties of a RC membrane can be obtained by surface-initiated ATRP. Copyright (C) 2010 John Wiley & Sons, Ltd.
引用
收藏
页码:1948 / 1952
页数:5
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