Crystal structure of tris(2-hydroxyethyl)ammonium bromide

被引：0
|
作者：
Yilmaz, VT [1 ]
Icbudak, H [1 ]
Olmez, H [1 ]
Howie, RA [1 ]
机构：
[1] UNIV ABERDEEN,DEPT CHEM,ABERDEEN AB9 2UE,SCOTLAND
来源：
TURKISH JOURNAL OF CHEMISTRY | 1996年 / 20卷 / 01期
关键词：
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The crystal structure of tris(2-hydroxyethyl)ammonium bromide, [HN(CH2CH2OH)(3)]BT, was determined as rhombohedral by single crystal X-ray diffractometer. The final R value was found to be 0.032 for 576 observed reflections. The crystal consists of layers of hydrogen-bonded cations, [HN(CH2CH2OH)(3)](+) and anions, Br-. Within a layer every cation donates and every anion accepts three hydrogen bonds. In the cation, trifurcated intramolecular hydrogen bonds are formed due to the surrounding of the hydrogen atom bonded to the N atom by the 2-hydroxyethyl groups.
引用
收藏
页码：69 / 73
页数：5
相关论文
共 50 条
  • [31] Tris(2-hydroxyethyl)ammonium arylchalcogenylacetates, growth stimulants of alcohol yeast Saccharomyces cerevisiae
    Privalova, E. A.
    Tiguntseva, N. P.
    Adamovich, S. N.
    Mirskov, R. G.
    Mirskova, A. N.
    RUSSIAN CHEMICAL BULLETIN, 2017, 66 (07) : 1320 - 1324
  • [32] Carcinostatic and protectoadaptation activity of tris-(2-hydroxyethyl)ammonium slats of arylheteroacetic acids
    Voronkov, M.G.
    Mirskova, A.N.
    Levskovskaya, G.G.
    Doklady Akademii Nauk, 2002, 386 (03) : 411 - 415
  • [33] Tris(2-hydroxyethyl)ammonium arylchalcogenylacetates, growth stimulants of alcohol yeast Saccharomyces cerevisiae
    E. A. Privalova
    N. P. Tiguntseva
    S. N. Adamovich
    R. G. Mirskov
    A. N. Mirskova
    Russian Chemical Bulletin, 2017, 66 : 1320 - 1324
  • [34] Bis(2-hydroxyethyl)ammonium picrate
    Nagapandiselvi, Perumal
    Gopalakrishnan, Rengasamy
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : O1455 - +
  • [35] ISOTYPIC STRUCTURES OF (I) TRI(2-HYDROXYETHYL)AMMONIUM HYDROGENSULFIDE AND (II) TRI(2-HYDROXYETHYL)AMMONIUM CHLORIDE
    MOOTZ, D
    BRODALLA, D
    WIEBCKE, M
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1990, 46 : 797 - 799
  • [36] MOLECULAR-STRUCTURE OF N-(2-HYDROXYETHYL)PYRIDINIUM BROMIDE
    KATAEVA, ON
    LITVINOV, IA
    STROBYKINA, IY
    KATAEV, VE
    BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1990, 39 (11): : 2371 - 2373
  • [37] New Method of Synthesis of Biologically Active Get(aryl)chalcogenylacetates of Tris(2-hydroxyethyl)ammonium
    Adamovich, S. N.
    Oborina, E. N.
    Ushakov, I. A.
    Mirskova, A. N.
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2018, 88 (10) : 2227 - 2229
  • [38] Synthesis and pharmacological activity of tris-(2-hydroxyethyl)ammonium 4-chlorophenylsulfonylacetate (sulfacetamine)
    A. N. Mirskova
    S. N. Adamovich
    R. G. Mirskov
    Pharmaceutical Chemistry Journal, 2012, 46 : 392 - 396
  • [39] New Method of Synthesis of Biologically Active Get(aryl)chalcogenylacetates of Tris(2-hydroxyethyl)ammonium
    S. N. Adamovich
    Е. N. Oborina
    I. А. Ushakov
    А. N. Mirskova
    Russian Journal of General Chemistry, 2018, 88 : 2227 - 2229
  • [40] Synthesis and pharmacological activity of tris-(2-hydroxyethyl)ammonium 4-chlorophenylsulfonylacetate (sulfacetamine)
    Mirskova, A. N.
    Adamovich, S. N.
    Mirskov, R. G.
    PHARMACEUTICAL CHEMISTRY JOURNAL, 2012, 46 (07) : 392 - 396
12345