Selective Dimerization of Aryl-substituted Terminal Alkynes on Bis(indenyl)zirconocene Derivatives

被引：7

作者：

Ren, Shenyong ^{[1
,2
,3
]}

Seki, Takashi ^{[4
]}

Necas, David ^{[1
,2
,3
]}

Shimizu, Hiroyuki ^{[5
]}

Nakajima, Kiyohiko ^{[6
]}

Kanno, Ken-ichiro ^{[1
,2
,3
]}

Song, Zhiying ^{[1
,2
,3
]}

Takahashi, Tamotsu ^{[1
,2
,3
]}

机构：

[1] Hokkaido Univ, Catalysis Res Ctr, Kita Ku, Sapporo, Hokkaido 0010021, Japan

[2] Hokkaido Univ, Grad Sch Pharmaceut Sci, Kita Ku, Sapporo, Hokkaido 0600812, Japan

[3] Japan Sci & Technol Agcy JST, SORST, Chiyoda Ku, Tokyo 1020075, Japan

[4] JX Nippon Oil & Energy Corp, Naka Ku, Yokohama, Kanagawa 2310815, Japan

[5] Japan Polyethylene Corp, Kawasaki Ku, Kawasaki, Kanagawa 2100865, Japan

[6] Aichi Univ Educ, Dept Chem, Kariya, Aichi 4488542, Japan

来源：

CHEMISTRY LETTERS | 2011年 / 40卷 / 12期

关键词：

INDENYL COMPLEXES; BENZENE-DERIVATIVES; COUPLING REACTIONS; RING-SLIPPAGE; CYCLOADDITION; ACETYLENES; REACTIVITY; CONVERSION; CHEMISTRY; ZIRCONACYCLOPENTADIENES;

D O I：

10.1246/cl.2011.1443

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Dimerization of aryl-substituted terminal alkynes on indenyl zirconium complexes occurred in a selective way. 1,4-Aryl-1,3-diene derivatives were formed exclusively after hydrolysis. It is in sharp contrast to the reaction on [Cp2Zr] complexes.

引用

页码：1443 / 1444

页数：2

共 50 条

[21] Aryl-substituted derivatives of trimethylenemethane dianion: a dynamic NMR study
Shenhar, R
Rabinovitz, M
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1997, (12): : 2463 - 2464
[22] Copolymerisation properties of siloxy-substituted bis(indenyl)zirconocene catalysts:: Modified rheological behaviour
Seppälä, J
Löfgren, B
Lehmus, P
Malmberg, A
MACROMOLECULAR SYMPOSIA, 2001, 173 : 227 - 235
[23] The synthesis of unnatural α-alkyl- and α-aryl-substituted serine derivatives
Narczyk, Aleksandra
Stecko, Sebastian
ORGANIC & BIOMOLECULAR CHEMISTRY, 2020, 18 (06) : 1204 - 1213
[24] REACTION OF ARYL-SUBSTITUTED GLYCINEAMIDINES WITH OXALIC-ACID DERIVATIVES
KORSHIN, EE
SOBOLEVA, GI
LEVIN, YA
PODVALNYI, EA
EFREMOV, YY
BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1991, 40 (01): : 212 - 214
[25] POLYMETALLIC DERIVATIVES OF ARYL-SUBSTITUTED ALKYNES .5. ALKYLATION OF PHENYLPROPYNE DIANION AND ITS ANALOGS IN LIQUID-AMMONIA
LIBMAN, NM
BRESTKIN, PA
KUZNETSOV, SG
ZHURNAL ORGANICHESKOI KHIMII, 1976, 12 (12): : 2566 - 2574
[26] Synthesis of new aryl-substituted methylphosphonic and methylenediphosphonic acids and their derivatives
Prishchenko, A. A.
Livantsov, M. V.
Novikova, O. P.
Livantsova, L. I.
Petrosyan, V. S.
RUSSIAN CHEMICAL BULLETIN, 2017, 66 (02) : 336 - 341
[27] Selective zirconocene hydride-catalyzed semi-hydrogenation of terminal alkynes
Kehner, Rebecca A.
Lubaev, Alexandra E.
Rathnayake, Manjula D.
Loden, Ryan
Zhang, Ge
Bayeh-Romero, Liela
TETRAHEDRON, 2023, 133
[28] Isospecific propylene polymerization with a novel 2-substituted bis(indenyl) ansa-zirconocene
Leino, R
Luttikhedde, H
Wilen, CE
Sillanpaa, R
Nasman, JH
ORGANOMETALLICS, 1996, 15 (10) : 2450 - 2453
[29] Group 1 and 13 complexes of aryl-substituted bis(phosphinimino)methyls
Hill, MS
Hitchcock, PB
Karagouni, SMA
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2004, 689 (04) : 722 - 730
[30] Ligand mediated iron catalyzed dimerization of terminal aryl alkynes: scope and limitations
Midya, Ganesh Chandra
Parasar, Bibudha
Dhara, Kalyan
Dash, Jyotirmayee
ORGANIC & BIOMOLECULAR CHEMISTRY, 2014, 12 (11) : 1812 - 1822

← 1 2 3 4 5 →