Redox Behavior of Ruthenium(Bipyridine)(Terpyridine)(Carbonyl) Complex-modified Carbon Electrode and Reactivity toward Electrochemical Reduction of CO2

被引：9
|
作者：
Tsukahara, Yuhei [1 ]
Wada, Tohru [1 ]
Tanaka, Koji [1 ]
机构：
[1] Inst Mol Sci, Coordinat Chem Labs, Okazaki, Aichi 4448787, Japan
来源：
CHEMISTRY LETTERS | 2010年 / 39卷 / 11期
关键词：
SELF-ASSEMBLED MONOLAYERS; DIAZONIUM SALTS; MULTIELECTRON REDUCTION; BOND FORMATION; SURFACES; PHOTOOXIDATION; LIGHT; GOLD;
D O I：
10.1246/cl.2010.1134
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Electrochemical reduction of a diazonium complex [Ru-(bpy)(trpy-ph-N-2(+))(CO)](PF6)(3) ([1](PF6)(3)) (bPY = dine, trpy-ph-N-2(+) = 4-(2,2' 6',2"-terpyncline-4'-yl)benzenedi-azonium) using a GC electrode forms multdayer films of the complexes on the electrode surface, on which the reduced form of the complex showed strong affinity toward CO2
引用
收藏
页码：1134 / 1135
页数：2
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