1,1-bis(phenylsulfonyl)-1-(pyridinio)methanide

被引:2
|
作者
Muir, KW [1 ]
Morris, DG
Ryder, KS
Varvoglis, A
机构
[1] Univ Glasgow, Dept Chem, Glasgow G12 8QQ, Lanark, Scotland
[2] Loughborough Univ Technol, Dept Chem, Loughborough LE11 3TU, Leics, England
[3] Univ Thessaloniki, Organ Chem Lab, GR-54006 Thessaloniki, Greece
关键词
D O I
10.1107/S0108270103010655
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The title disulfonyl-stabilized pyridinium ylide, C5H5N+C-(SO2C6H5)(2) or C18H15NO4S2, contains a near planar NCS2 core. The structure suggests that the formal negative charge of the ylide C atom is delocalized to the S atoms rather than the N atom. Structural features of pyridinium ylides are briefly discussed.
引用
收藏
页码:O376 / O377
页数:2
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