The development and characterization of a novel coagulant for dust suppression in open-cast coal mines

被引:40
|
作者
Zhou, Gang [1 ,2 ]
Fan, Tao [1 ]
Xu, Mao [1 ]
Qiu, Han [1 ]
Wang, Jiayuan [1 ]
Qiu, Lei [1 ]
机构
[1] Shandong Univ Sci & Technol, Coll Min & Safety Engn, Qingdao, Shandong, Peoples R China
[2] China Univ Min & Technol, Sch Safety Engn, Xuzhou, Peoples R China
基金
中国国家自然科学基金; 中国博士后科学基金;
关键词
Dust from open-cast mines; lignosulfonate; acrylic acid; acrylamide; graft copolymerization; coagulant; COMBUSTION;
D O I
10.1177/0263617417711025
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
This paper proposes the development of a novel coagulant for dust suppression in open-cast mines. Specifically, pretreated sodium lignin sulfonate and acrylic acid were first cross-linked, then the graft copolymerization of the intermediate product (the cross-linking product) and acrylamide was conducted and finally the resulting gelatinous substances were crushed. During the reaction process, N,N'-methylene-bis-acrylamide and ammonium persulfate were used as the cross-linking agent and initiator, respectively. Subsequently, the functional groups, crystalline structure, and thermal stability of the dust coagulant were examined by means of Fourier transform infrared spectra measurements, X-ray diffraction spectra measurements, and differential scanning calorimeter analysis. Moreover, single-factor experiments were conducted to explore the optimal synthesis condition. According to the experimental results, the coagulant achieved its optimal dust suppression performance under the following conditions: the mass ratio of lignin to acrylic acid was 1:3, the mass ratio of lignin to acrylamide was 2:7, the content of the cross-linking agent was 0.9%, the mass ratio of initiator to acrylamide was 2:100, the reaction temperature was set as 60?, and the pH value was set as 7. Finally, the coagulant was measured for its swelling kinetics, viscosity, film-forming hardness, peeling strength, and ability to suppress dust. It can be concluded that the coagulant exhibits a very high standard of both dust suppression and wind resistance.
引用
收藏
页码:608 / 624
页数:17
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