Exploiting cooperative binding of ion-pair to boost anion recognition in water/acetonitrile mixtures

被引：3
|
作者：
Zalubiniak, Dominika [1 ]
Kos, Joanna [1 ]
Piatek, Piotr [1 ]
机构：
[1] Univ Warsaw, Dept Chem, Pasteura 1, PL-02093 Warsaw, Poland
来源：
TETRAHEDRON | 2017年 / 73卷 / 51期
关键词：
Supramolecular chemistry; Salt receptor; Recognition in water; Binding cooperation; RECEPTOR CHEMISTRY HIGHLIGHTS; HETERODITOPIC SALT RECEPTOR; SELECTIVITY; ROTAXANE; CATIONS; HALIDE; WATER;
D O I：
10.1016/j.tet.2017.10.077
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An L-arginine based compound was designed and prepared as a heteroditopic ion-pair receptor. The cation binding is provided by a sodium selective N-acyl-aza-18-crown-6 subunit whereas for anion complexation, urea and guanidinium groups were introduced. As shown by H-1 NMR titrations this receptor is capable of binding sodium halide ion-pairs in solutions containing up to 20% of water. The halide binding is stronger in the presence of co-coordinated sodium cation than in the presence of non coordinated TBA cation. (C) 2017 Elsevier Ltd. All rights reserved.
引用
收藏
页码：7190 / 7194
页数：5
相关论文
共 50 条
  • [21] Ion-pair extraction of metalloporphyrins into acetonitrile for determination of copper(II)
    Tabata, M
    Kumamoto, M
    Nishimoto, J
    ANALYTICAL CHEMISTRY, 1996, 68 (05) : 758 - 762
  • [22] Ion-pair extraction of metalloporphyrins into acetonitrile for determination of copper(II)
    Anal Chem, 5 (758):
  • [23] Ion Solvation in Water–Acetonitrile Mixtures
    R. D. Mountain
    International Journal of Thermophysics, 2001, 22 : 101 - 110
  • [24] Ditopic Covalent Cage for Ion-Pair Binding: Influence of Anion Complexation on the Cation Exchange Rate
    Delecluse, Magalie
    Manick, Anne-Doriane
    Chatelet, Bastien
    Chevallier-Michaud, Sabine
    Moraleda, Delphine
    de Riggi, Innocenzo
    Dutasta, Jean-Pierre
    Martinez, Alexandre
    CHEMPLUSCHEM, 2024, 89 (04):
  • [25] Anion and cation binding by a new indole/pyridine/amine-based ion-pair receptor
    Skala, Kristin N.
    Perkins, Katelyn G.
    Ali, Amna
    Kutlik, Robert
    Summitt, Addle M.
    Swamy-Mruthinti, Satyanarayana
    Khan, Farooq A.
    Fujita, Megumi
    TETRAHEDRON LETTERS, 2010, 51 (50) : 6516 - 6520
  • [26] ION-PAIR BINDING BY A UREA IN CHLOROFORM SOLUTION
    SMITH, PJ
    REDDINGTON, MV
    WILCOX, CS
    TETRAHEDRON LETTERS, 1992, 33 (41) : 6085 - 6088
  • [27] Photoreduction of 4,4′-bipyridine by amines in acetonitrile-water mixtures:: Influence of H-bonding on the ion-pair structure and dynamics
    Poizat, O
    Buntinx, G
    Boilet, L
    JOURNAL OF PHYSICAL CHEMISTRY A, 2005, 109 (48): : 10813 - 10823
  • [28] Thermodynamic studies on the formation of ion-pair cobalt complexes in acetone-water mixtures
    Amira, Mohamed F.
    El-Sisy, Nader Said
    Zaghloul, Amal A.
    JOURNAL OF CHEMICAL THERMODYNAMICS, 2024, 199
  • [29] Highly Cooperative Binding of Ion-Pair Dimers and Ion Quartets by a Bis(calix[4]pyrrole) Macrotricyclic Receptor
    Valderrey, Virginia
    Escudero-Adan, Eduardo C.
    Ballester, Pablo
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (27) : 6898 - 6902
  • [30] ESR STUDY OF BENZENE ANION RADICAL ION-PAIR EQUILIBRIA
    JONES, MT
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1975, (169): : 52 - 52
12345